The Zn-Rich Corner of the 450 °C Isothermal Section of the Zn-Fe-Ni-Sb Quaternary System

被引：1
作者：
Zhu, Zhongxi [1 ,2 ]
Xu, Qilin [1 ,2 ]
Chen, Meiliang [1 ,2 ]
Yin, Fucheng [1 ,2 ]
Li, Zhi [1 ,2 ]
机构：
[1] Xiangtan Univ, Key Lab Mat Design & Preparat Technol Hunan Prov, Xiangtan 411105, Hunan, Peoples R China
[2] Xiangtan Univ, Sch Mech Engn, Xiangtan 411105, Hunan, Peoples R China
来源：
JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION | 2014年 / 35卷 / 05期
基金：
中国国家自然科学基金;
关键词：
phase diagram; x-ray diffraction (XRD); zinc-based alloy; Zn-Fe-Ni-Sb; TERNARY PHASE-DIAGRAM; DIP-GALVANIZED STEEL; A-DEGREES-C; CRYSTAL-STRUCTURE; 570; K; ZINC; SILICON; BI; 450-DEGREES-C; REACTIVITY;
D O I：
10.1007/s11669-014-0320-z
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The 450 degrees C isothermal section of the Zn-Fe-Ni-Sb quaternary system with Zn fixed at 93 at.% has been studied experimentally using scanning electron microscopy coupled with energy dispersive x-ray spectroscopy and x-ray diffraction. The (L + T-FeNiZn) field is found to be coexistent with all other phase fields in the section, except the (zeta-FeZn + Sb2Zn3) field. The Sb solubility in the zeta-FeZn phase is very limited, and it almost insoluble in the delta-NiZn phase. The solubilities of Fe and Ni in the Sb2Zn3 phase are 0.6 and 0.9 at.%, respectively. The maximum solubility of Sb in the gamma-NiZn phase is 1.9 at.%. Three four-phase regions and two three-phase regions have been confirmed experimentally in this isothermal section. In addition, no new phase was found in the study.
引用
收藏
页码：555 / 563
页数：9
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