Microporous Polymers from a Carbazole-Based Triptycene Monomer: Synthesis and Their Applications for Gas Uptake

被引：36

作者：

Zhai, Tian-Long ^{[1
]}

Tan, Liangxiao ^{[2
]}

Luo, Yi ^{[1
]}

Liu, Jun-Min ^{[3
]}

Tan, Bien ^{[2
]}

Yang, Xiang-Liang ^{[1
]}

Xu, Hui-Bi ^{[1
]}

Zhang, Chun ^{[1
]}

机构：

[1] Huazhong Univ Sci & Technol, Coll Life Sci & Technol, Natl Engn Res Ctr Nanomed, Key Lab Mol Biophys,Minist Educ, Hubei 430074, Peoples R China

[2] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Hubei 430074, Peoples R China

[3] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2016年 / 11卷 / 02期

基金：

中国国家自然科学基金;

关键词：

gas adsorption; microporous materials; polymers; synthesis; triptycene; INTRINSIC MICROPOROSITY; SURFACE-AREA; STORAGE; DESIGN; RECOGNITION; STRATEGY; FILMS;

D O I：

10.1002/asia.201501105

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two kinds of novel organic microporous polymers TCPs (TCP-A and TCP-B) were prepared by two cost-effective synthetic strategies from the monomer of tricarbazolyltriptycene (TCT). Their structure and properties were characterized by FT-IR, solid (CNMR)-C-13, powder XRD, SEM, TEM, and gas absorption measurements. TCP-B displayed a high surface area (1469m(2)g(-1)) and excellent H-2 storage (1.70wt% at 1bar/77K) and CO2 uptake abilities (16.1wt% at 1bar/273K), which makes it a promising material for potential application in gas storage.

引用

页码：294 / 298

页数：5

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