The Drosophila of single-molecule magnetism: [Mn12O12(O2CR)16(H2O)4]

被引：594
作者：
Bagai, Rashmi [1 ]
Christou, George [1 ]
机构：
[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
来源：
CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 04期
关键词：
JAHN-TELLER ISOMERISM; HIGH-SPIN MOLECULES; STRUCTURAL-CHARACTERIZATION; MAGNETIZATION RELAXATION; ELECTRON REDUCTION; MN-12; COMPLEXES; CARBOXYLATE; SYMMETRY; CLUSTER; ACETATE;
D O I：
10.1039/b811963e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Single-molecule magnets (SMMs) are individual molecules that can function as nanoscale magnetic particles. The [Mn12O12(O2CR)(16)(H2O)(4)] (Mn-12; R = Me, Et, etc.) family of SMMs was the first one discovered; it is also the one whose study has provided the majority of current knowledge on this interesting magnetic phenomenon, prompting its description here as the Drosophila of the field. This tutorial review will survey the various chemical studies that have been carried out to date on this family. This will include a discussion of methods that have been developed for their structural and redox transformation, and the effect of the latter on the magnetic and SMM properties.
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页码：1011 / 1026
页数：16
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