Mechanistic Manifold and New Developments of the Julia-Kocienski Reaction

被引：234

作者：

Aissa, Christophe ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 2009卷 / 12期

关键词：

Olefination; Modified Julia-Kocienski reaction; Sulfones; ENANTIOSELECTIVE TOTAL-SYNTHESIS; STEREOCONTROLLED TOTAL-SYNTHESIS; FORMAL TOTAL-SYNTHESIS; HIGH-YIELD SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; CONVERGENT SYNTHESIS; 3,5-BIS(TRIFLUOROMETHYL)PHENYL SULFONES; ALPHA; BETA-UNSATURATED ESTERS; BENZOTHIAZOLYL SULFONES; CARBONYL-COMPOUNDS;

D O I：

10.1002/ejoc.200801117

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Julia-Kocienski reaction has become indispensable in the synthetic organic chemist's olefination toolbox. Although the stereochemical outcome of the transformation is sometimes difficult to predict, some trends can be explained by an array of mechanistic hypotheses which have been put forward since the initial disclosure of the reaction. Moreover, several important developments have been recently reported and are summarised in this microreview. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：1831 / 1844

页数：14

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