Synthesis and characterization of epoxy encapsulating silica microcapsules and amine functionalized silica nanoparticles for development of an innovative self-healing concrete

被引：85

作者：

Perez, G. ^{[1
]}

Erkizia, E. ^{[2
]}

Gaitero, J. J. ^{[2
]}

Kaltzakorta, I. ^{[2
]}

Jimenez, I. ^{[1
]}

Guerrero, A. ^{[1
]}

机构：

[1] CSIC, Inst Construct Sci Eduardo Torroja, E-28033 Madrid, Spain

[2] Geldo, Sustainable Construct Div, Mat, Tecnalia, Derio 48160, Spain

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2015年 / 165卷

关键词：

Composite materials; Chemical synthesis; Chemical techniques; Microstructure; CONTROLLED-RELEASE; COMPOSITES; EMULSION;

D O I：

10.1016/j.matchemphys.2015.08.047

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Silica microcapsules encapsulating an epoxy compound (CAP) and silica nanoparticles functionalized by an amine group (NS) are synthesized to be used as self-healing system for smart cementitious composites. The innovative character of this system comes from the use of silica shell microcapsules to improve the durability and compatibility with the cement and from the use of functionalized nanosilica to obtain an amine functionalized cementitious matrix. Characterization of the particles indicates that they are amorphous and possess a proper morphology and size to be considered as additions to cement. The stability of the epoxy compound inside the microcapsules and the presence of amine groups bonded to silica nanoparticles are also confirmed. Moreover, NS shows a pozzolanic activity superior to that of the silica fume used as reference, while CAP is to a high degree stable upon reaction with lime. The results confirm that the synthesized particles are a suitable starting point to address the development of a smart self-healing concrete. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：39 / 48

页数：10

共 31 条

[1] Core/shell silica-based in-situ microencapsulation:: A self-templating method [J].

Ahn, BY ;

Seok, SI ;

Baek, IC ;

Hong, SI .

CHEMICAL COMMUNICATIONS, 2006, (02) :189-190

[2] Sol-gel matrices for controlled release:: from macro to nano using emulsion polymerisation [J].

Barbe, Christophe J. ;

Kong, Linggen ;

Finnie, Kim S. ;

Calleja, Sandrine ;

Hanna, John V. ;

Drabarek, Elizabeth ;

Cassidy, David T. ;

Blackford, Mark G. .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2008, 46 (03) :393-409

[3]

Berriozabal G., 2011, THESIS UPV EHU

[4] Synthesis and characterisation of silica nanoparticles bearing different functional groups obtained via a two-stage method [J].

Berriozabal, Gemma ;

de Miguel, Yolanda R. .

PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 7, NO 11-12, 2010, 7 (11-12) :2692-2696

[5] Self-Healing Polymers and Composites [J].

Blaiszik, B. J. ;

Kramer, S. L. B. ;

Olugebefola, S. C. ;

Moore, J. S. ;

Sottos, N. R. ;

White, S. R. .

ANNUAL REVIEW OF MATERIALS RESEARCH, VOL 40, 2010, 40 :179-211

[6]

Brinker J.C., 1990, SOL GEL SCI PHYS CHE

[7] Ceramic micro-particles synthesised using emulsion and sol-gel technology:: An investigation into the controlled release of encapsulants and the tailoring of micro-particle size [J].

Bush, AJ ;

Beyer, R ;

Trautman, R ;

Barbé, CJ ;

Bartlett, JR .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2004, 32 (1-3) :85-90

[8] Influence of the microsilica state on pozzolanic reaction rate [J].

de Rojas, MIS ;

Rivera, J ;

Frías, M .

CEMENT AND CONCRETE RESEARCH, 1999, 29 (06) :945-949

[9] Formation of silica nanoparticles in microemulsions [J].

Finnie, Kim S. ;

Bartlett, John R. ;

Barbe, Christophe J. A. ;

Kong, Linggen .

LANGMUIR, 2007, 23 (06) :3017-3024

[10] SPECIFIC FEATURES OF THE IR-SPECTRA OF SILICATE-GLASSES [J].

HANDKE, M ;

MOZGAWA, W ;

NOCUN, M .

JOURNAL OF MOLECULAR STRUCTURE, 1994, 325 :129-136

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