The synthesis of a 3d-4f polynuclear metal cluster under microwave irradiation: crystal structure and magnetic property of [La3Ni6(IDA)6(OH)6(H2O)12]•3NO3•15H2O (IDA = iminodiacetate)

被引：26
|
作者：
Zhuang, Gui-Lin
Sun, Xiao-Jun
Long, La-Sheng [1 ]
Huang, Rong-Bin
Zheng, Lan-Sun
机构：
[1] Xiamen Univ, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Peoples R China
来源：
DALTON TRANSACTIONS | 2009年 / 24期
关键词：
SINGLE-MOLECULE MAGNETS; TRIGONAL PRISMATIC CLUSTERS; IONS; LN; COMPLEX; LA; SPECTRA; SERIES; WHEEL;
D O I：
10.1039/b823294f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A cage-shaped 3d-4f heterometallic ferromagnetic cluster, consisting of six Ni(II) and three La(III) ions, was synthesized by microwave irradiation. Themagnetic susceptibilities of the cluster were fitted with the help of the program MAGPACK, revealing that the magnetic exchange in the cluster is closely related to the coordination mode and spatial distribution between the metal ions.
引用
收藏
页码：4640 / 4642
页数：3
相关论文
共 50 条
  • [31] Magnetic relaxation in basic iron(III) carboxylate [Fe3O(O2CPh)6(H2O)3]ClO4•py
    Georgopoulou, Anastasia N.
    Sanakis, Yiannis
    Boudalis, Athanassios K.
    DALTON TRANSACTIONS, 2011, 40 (24) : 6371 - 6374
  • [32] Synthesis and molecular structure of nine-coordinate complex K3[Y(NTA)2(H2O)]•6H2O
    Wang, J
    Zhang, XD
    Ma, R
    Fan, DM
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2001, 17 (01) : 119 - 123
  • [33] Synthesis, characterization and crystal structure of [Er(nmp)4(H2O)3]H[SiMo12O40]•2nmp•0.5H2O
    Wang, JP
    Han, QX
    Niu, JY
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (04) : 425 - 430
  • [34] Synthesis, crystal structure, thermal, photoluminescent and magnetic properties of a new material: Na2[Ni(C2O4)2(H2O)2]•6H2O
    Narsimhulu, M.
    Kumar, G. Anil
    Bhargavi, G.
    Srinivas, B.
    Hussain, K. A.
    JOURNAL OF MOLECULAR STRUCTURE, 2019, 1178 : 155 - 161
  • [35] Synthesis and Structures of the Capped and Sandwiched Cobalt Heptamolybdate Polyoxometalate (NH4)6{[Co(H2O)5][Mo7O24][Co(H2O)2][Mo7O24][Co(H2O)5]} • 6 H2O and Its Extended Structure (NH4)6{[Co(H2O)2]3[Mo7O24]2}
    Spriet, Matthieu R.
    Polinski, Matthew J.
    Mercado, Brandon Q.
    Villa, Eric M.
    CRYSTALS, 2022, 12 (09)
  • [36] Supertetrahedral T2 clusters in 3d-4f {Fe4Ln6}: Synthesis, crystal structure, magnetic and photoluminescent properties
    Akhtar, Muhammad Nadeem
    Liao, Xiao-Fen
    Chen, Yan-Cong
    AlDamen, Murad A.
    Huang, Guo-Zhang
    Liu, Jun-Liang
    Khan, Javid
    Tong, Ming-Liang
    INORGANICA CHIMICA ACTA, 2018, 482 : 240 - 245
  • [37] The B(C6F5)3•H2O promoted synthesis of fluoroalkylated 3,3′,3′′-trisindolylmethanes from fluorocarboxylic acids and indoles
    Xu, Xin
    Gao, Dandan
    Wang, Jiahua
    Tang, Xiang-Ying
    Wang, Long
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2023, 21 (07) : 1478 - 1486
  • [38] [Zn(HPO3)(C11N2O2H12)] and [Zn3(H2O)(PO4)(HPO4)(C6H9N3O2)2 (C6H8N3O2)]: homochiral zinc phosphite/phosphate networks with biofunctional amino acids
    Dong, Zhaojun
    Zhao, Lang
    Liang, Zhiqiang
    Chen, Peng
    Yan, Yan
    Li, Jiyang
    Yu, Jihong
    Xu, Ruren
    DALTON TRANSACTIONS, 2010, 39 (23) : 5439 - 5445
  • [39] Syntheses and structures of p-HOOCC6F4COOH • H2O (H2L • H2O) and luminescent coordination polymers [Tb2(H2O)4(L)3 • 2H2O] n and Tb2(Phen)2(L)3 • 2H2O
    Larionov, S. V.
    Myachina, L. I.
    Glinskaya, L. A.
    Korol'kov, I. V.
    Uskov, E. M.
    Antonova, O. V.
    Karpov, V. M.
    Platonov, V. E.
    Fadeeva, V. P.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2012, 38 (12) : 717 - 723
  • [40] Luminescence of (H3O)Al3(SO4)2(OH)6:Cu synthesized under hydrothermal condition
    Kuroki, Yuichiro
    Iwata, Nobuyuki
    Okamoto, Tomoichiro
    Takata, Masasuke
    CERAMICS INTERNATIONAL, 2012, 38 : S567 - S569
12345