The synthesis of a 3d-4f polynuclear metal cluster under microwave irradiation: crystal structure and magnetic property of [La3Ni6(IDA)6(OH)6(H2O)12]•3NO3•15H2O (IDA = iminodiacetate)

被引：26
作者：
Zhuang, Gui-Lin
Sun, Xiao-Jun
Long, La-Sheng [1 ]
Huang, Rong-Bin
Zheng, Lan-Sun
机构：
[1] Xiamen Univ, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Peoples R China
来源：
DALTON TRANSACTIONS | 2009年 / 24期
关键词：
SINGLE-MOLECULE MAGNETS; TRIGONAL PRISMATIC CLUSTERS; IONS; LN; COMPLEX; LA; SPECTRA; SERIES; WHEEL;
D O I：
10.1039/b823294f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A cage-shaped 3d-4f heterometallic ferromagnetic cluster, consisting of six Ni(II) and three La(III) ions, was synthesized by microwave irradiation. Themagnetic susceptibilities of the cluster were fitted with the help of the program MAGPACK, revealing that the magnetic exchange in the cluster is closely related to the coordination mode and spatial distribution between the metal ions.
引用
收藏
页码：4640 / 4642
页数：3
相关论文
共 32 条
[21]   The beauty of symmetry [J].
Müller, A .
SCIENCE, 2003, 300 (5620) :749-750
[22]   Mixed 3d/4d and 3d/4f metal clusters:: Tetranuclear FeIII2MIII2 (MIII = Ln, Y) and MnIV2MIII2 (M = Yb, Y) complexes, and the first Fe/4f single-molecule magnets [J].
Murugesu, M ;
Mishra, A ;
Wernsdorfer, W ;
Abboud, KA ;
Christou, G .
POLYHEDRON, 2006, 25 (02) :613-625
[23]   A tetranuclear 3d-4f single molecule magnet:: [CuIILTbIII(hfac)2]2 [J].
Osa, S ;
Kido, T ;
Matsumoto, N ;
Re, N ;
Pochaba, A ;
Mrozinski, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (02) :420-421
[24]  
Rodríguez-Fortea A, 2001, CHEM-EUR J, V7, P627, DOI 10.1002/1521-3765(20010202)7:3<627::AID-CHEM627>3.0.CO
[25]  
2-I
[26]   Strategies for constructing diverse chiral environments in multimetallic bifunctional asymmetric catalysis [J].
Shibasaki, Masakatsu ;
Matsunaga, Shigeki ;
Kumagai, Naoya .
SYNLETT, 2008, (11) :1583-1602
[27]   Colloidal synthesis and characterization of ultrasmall perovskite GdFeO3 nanocrystals [J].
Soderlind, Fredrik ;
Fortin, Marc A. ;
Petoral, Rodrigo M., Jr. ;
Klasson, Anna ;
Veres, Teodor ;
Engstrom, Maria ;
Uvdal, Kajsa ;
Kall, Per-Olov .
NANOTECHNOLOGY, 2008, 19 (08)
[28]   Template synthesis and single-molecule magnetism properties of a complex with spin S=16 and a [Mn8O8]8+ saddle-like core [J].
Tasiopoulos, AJ ;
Wernsdorfer, W ;
Moulton, B ;
Zaworotko, MJ ;
Christou, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (50) :15274-15275
[29]   Tunable luminescent lanthanide coordination polymers based on reversible solid-state ion-exchange monitored by ion-dependent photoinduced emission spectra [J].
Wang, Peng ;
Ma, Jian-Ping ;
Dong, Yu-Bin ;
Huang, Ru-Qi .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (35) :10620-+
[30]   [GdNi6] and [LaNi6]:: High-field EPR spectroscopy and magnetic studies of exchange-coupled octahedral clusters [J].
Yukawa, Y ;
Aromí, GA ;
Igarashi, S ;
Ribas, J ;
Zvyagin, SA ;
Krzystek, J .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (13) :1997-2001
1234