Cyclopalladate complex of 3-benzyl-7-methyl-3,7-diazabicyclo[3.3.1]nonane

被引：5
|
作者：
Bulygina, L. A. [1 ]
Khrushcheva, N. S. [1 ]
Peregudov, A. S. [1 ]
Sokolov, V. I. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, 28 Ul Vavilova, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2016年 / 65卷 / 10期
关键词：
bispidines; palladacycles; catalysts; Heck reaction; Suzuki reaction; hydroarylation; norbornene; CROSS-COUPLING REACTION; PALLADIUM COMPLEXES; PALLADACYCLES; CATALYSTS; HECK; SUBSTITUTION; DERIVATIVES;
D O I：
10.1007/s11172-016-1610-x
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new (C,N,N)-pincer cyclopalladate unsymmetrical complex of 3-benzyl-7-methyl-3,7-diazabicyclo[3.3.1]nonane (3-benzyl-7-methylbispidine) was synthesized and characterized. Catalytic performance of this complex was examined in the Heck and Suzuki reactions and in the norbornene hydroarylation.
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页码：2479 / 2484
页数：6
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