Cyclopalladate complex of 3-benzyl-7-methyl-3,7-diazabicyclo[3.3.1]nonane

被引:5
作者
Bulygina, L. A. [1 ]
Khrushcheva, N. S. [1 ]
Peregudov, A. S. [1 ]
Sokolov, V. I. [1 ]
机构
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, 28 Ul Vavilova, Moscow 119991, Russia
关键词
bispidines; palladacycles; catalysts; Heck reaction; Suzuki reaction; hydroarylation; norbornene; CROSS-COUPLING REACTION; PALLADIUM COMPLEXES; PALLADACYCLES; CATALYSTS; HECK; SUBSTITUTION; DERIVATIVES;
D O I
10.1007/s11172-016-1610-x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new (C,N,N)-pincer cyclopalladate unsymmetrical complex of 3-benzyl-7-methyl-3,7-diazabicyclo[3.3.1]nonane (3-benzyl-7-methylbispidine) was synthesized and characterized. Catalytic performance of this complex was examined in the Heck and Suzuki reactions and in the norbornene hydroarylation.
引用
收藏
页码:2479 / 2484
页数:6
相关论文
共 25 条
[1]  
Alonso DA, 2002, ADV SYNTH CATAL, V344, P172, DOI 10.1002/1615-4169(200202)344:2<172::AID-ADSC172>3.0.CO
[2]  
2-9
[3]   Toward the Ideal Catalyst: From Atomic Centers to a "Cocktail" of Catalysts [J].
Ananikov, Valentine P. ;
Beletskaya, Irina P. .
ORGANOMETALLICS, 2012, 31 (05) :1595-1604
[4]   Palladacycles in catalysis - a critical survey [J].
Beletskaya, IP ;
Cheprakov, AV .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (24) :4055-4082
[5]   SYNTHESIS AND METAL-COMPLEXES OF SYMMETRICALLY N-SUBSTITUTED BISPIDINONES [J].
BLACK, DS ;
DEACON, GB ;
ROSE, M .
TETRAHEDRON, 1995, 51 (07) :2055-2076
[6]   Synthesis, characterization and catalytic activity in Heck-type reactions of orthometallated PdII and PtII complexes derived from (1R,2R)-1,2-diaminocyclohexane [J].
Bravo, J ;
Cativiela, C ;
Navarro, R ;
Urriolabeitia, EP .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 650 (1-2) :157-172
[7]   Chiral bispidines [J].
Breuning, Matthias ;
Steiner, Melanie .
SYNTHESIS-STUTTGART, 2008, (18) :2841-2867
[8]   Visible-Light Photoredox in Homolytic Aromatic Substitution: Direct Arylation of Arenes with Aryl Halides [J].
Cheng, Yannan ;
Gu, Xiangyong ;
Li, Pixu .
ORGANIC LETTERS, 2013, 15 (11) :2664-2667
[9]   Synthesis and Coordination Chemistry of N,N-Diallylbispidine [J].
Cui, Huiling ;
Goddard, Richard ;
Poerschke, Klaus-Richard .
ORGANOMETALLICS, 2011, 30 (22) :6241-6252
[10]  
Gogoll A, 2001, CHEM-EUR J, V7, P396, DOI 10.1002/1521-3765(20010119)7:2<396::AID-CHEM396>3.0.CO