Towards stable and commercially available perovskite solar cells

被引:1031
作者
Park, Nam-Gyu [1 ]
Gratzel, Michael [2 ]
Miyasaka, Tsutomu [3 ]
Zhu, Kai [4 ]
Emery, Keith [4 ]
机构
[1] Sungkyunkwan Univ, Sch Chem Engn, Suwon 440746, South Korea
[2] Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, Sch Basic Sci, CH-1015 Lausanne, Switzerland
[3] Toin Univ Yokohama, Grad Sch Engn, Aoba Ku, Yokohama, Kanagawa 2258503, Japan
[4] Natl Renewable Energy Lab, Golden, CO 80401 USA
基金
瑞士国家科学基金会; 新加坡国家研究基金会;
关键词
HALIDE PEROVSKITES; CH3NH3PBI3; PEROVSKITE; CHARGE EXTRACTION; GRAIN-BOUNDARY; BASE ADDUCT; EFFICIENT; DEGRADATION; LIGHT; RECOMBINATION; HYSTERESIS;
D O I
10.1038/NENERGY.2016.152
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Solar cells employing a halide perovskite with an organic cation now show power conversion efficiency of up to 22%. However, these cells are facing issues towards commercialization, such as the need to achieve long-term stability and the development of a manufacturing method for the reproducible fabrication of high-performance devices. Here, we propose a strategy to obtain stable and commercially viable perovskite solar cells. A reproducible manufacturing method is suggested, as well as routes to manage grain boundaries and interfacial charge transport. Electroluminescence is regarded as a metric to gauge theoretical efficiency. We highlight how optimizing the design of device architectures is important not only for achieving high efficiency but also for hysteresis-free and stable performance. We argue that reliable device characterization is needed to ensure the advance of this technology towards practical applications. We believe that perovskite-based devices can be competitive with silicon solar modules, and discuss issues related to the safe management of toxic material.
引用
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页数:8
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