Biogenic synthesis of cellulose supported Pd(0) nanoparticles using hearth wood extract of Artocarpus lakoocha Roxb - A green, efficient and versatile catalyst for Suzuki and Heck coupling in water under microwave heating

被引：56

作者：

Baruah, Diganta ^{[1
]}

Das, Ram Nath ^{[1
]}

Hazarika, Swapnali ^{[2
]}

Konwar, Dilip ^{[1
]}

机构：

[1] CSIR North East Inst Sci & Technol, Synthet Organ Chem Div, Jorhat 785006, Assam, India

[2] CSIR North East Inst Sci & Technol, Div Chem Engn, Jorhat 785006, Assam, India

来源：

CATALYSIS COMMUNICATIONS | 2015年 / 72卷

关键词：

Cellulose; Oxyresveratrol; Biogenic; Suzuki-Heck; Green; IMIDAZOLIUM IONIC LIQUID; STILBENES RESVERATROL; CU-NANOPARTICLES; PALLADIUM; PD; OXYRESVERATROL; SOLVENT;

D O I：

10.1016/j.catcom.2015.09.011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A simple, convenient and green protocol has been developed for the synthesis of cellulose supported Pd(0) nanoparticles (NPs) using hearth wood extract of Artocarpus lakoocha Roxb-as a bioreductant. Novel one-step method for the isolation of active bioreductant oxyresveratrol (2,3', 4, 5'-tetrahydroxy-trans-stilbene) present in the hearth wood extract of A. lakoocha Roxb is also disclosed. Synthesized cellulose supported Pd(0) NPs have been used as an efficient catalyst for Suzuki and Heck coupling reactions in water under microwave irradiation. The prepared Pd(0) NPs were characterized by Ultraviolet-visible (UV-vis), Fourier transform-infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and Transmission electron microscopy (TEM). The catalyst can be recycled up-to ten times without losing its activity significantly. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：73 / 80

页数：8

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