A simple scaling for the core-shell nanostructure formed by self-assembly of block copolymers in a selective solvent

被引：21
作者：
Wu, C [1 ]
Gao, J
机构：
[1] Chinese Univ Hong Kong, Dept Chem, Shatin, NT, Peoples R China
[2] Univ Sci & Technol China, Dept Chem Phys, Open Lab Bond Select Chem, Hefei 230026, Anhui, Peoples R China
来源：
MACROMOLECULES | 2000年 / 33卷 / 02期
关键词：
D O I：
10.1021/ma990288g
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A simple scaling model is presented for the polymeric core-shell nanostructure formed through the self-assembly of block copolymer poly(ethylene oxide)-b-poly(propylene oxide) in a selective solvent. The radius of the core (Rc) and the thickness of the shell can be scaled to the copolymer composition, such that Rc-1∝m/n and δ∝m2/3, where m and n are the numbers of the repeating units of the soluble and insoluble blocks in a AmBn or AmBnAm type block copolymers.
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页码：645 / 646
页数：2
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