Reactions of laser-ablated palladium and platinum atoms with ethylene: An infrared study of the palladium complex and platinum insertion product isolated in solid argon

被引：14

作者：

Cho, HG ^{[1
]}

Andrews, L ^{[1
]}

机构：

[1] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2004年 / 108卷 / 30期

关键词：

D O I：

10.1021/jp049355l

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reactions of laser-ablated palladium and platinum atoms with ethylene isotopomers have been carried out in excess argon during condensation at 7 K. Infrared spectra show that palladium forms a pi complex with ethylene whereas platinum generates an insertion product. Acetylene is a major product, suggesting that H-2 elimination from ethylene is also induced by the metal atom reactions. Product frequencies calculated by DFT are compared with the experimental values.

引用

页码：6272 / 6278

页数：7

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