Studies on some acrylamido polymers and copolymer as stabilizers for nitrocellulose

被引:16
作者
Hassan, MA [1 ]
Shehata, AB [1 ]
机构
[1] Natl Inst Stand, Giza 12211, Egypt
关键词
monomer synthesis; polymerization; copolymerization; propellant; stabilizers; thermal analysis;
D O I
10.1002/app.10834
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
para-Phenylene diamine was reacted with diethylmalonate and the product was reacted with acryloyl chloride to obtain the corresponding acrylamido malonanilide monomer. para-Nitro aniline was also reacted with acryloyl chloride to obtain the corresponding monomer. The two monomers were homopolymerized and then copolymerized, The obtained homopolymers and the copolymer were mixed with nitrocellulose and evaluated using thermal analysis and Bergmann-Junk techniques as propellant stabilizers in comparison with the common stabilizer, centralite 1. It was found that the homopolymer containing the p-nitro group is a superior stabilizer. (C) 2002 Wiley Periodicals, Inc.
引用
收藏
页码:2808 / 2819
页数:12
相关论文
共 10 条
[1]  
[Anonymous], 1984, PROPELLANTS EXPLOS P
[2]  
AYYANGAR NR, 1988, Patent No. 161612
[4]  
GIBSON JD, 1984, Patent No. 4478656
[5]  
KIRSCHE EJ, 1987, Patent No. 4659403
[6]  
NOBELKURT B, 1960, ANAL METHODS POWDERS
[7]  
Ozawa TB, 1965, B CHEM SOC JPN, V38, P188
[8]   Acrylonitrile-butadiene rubber stabilized by methacrylamides as antioxidants [J].
Shehata, AB ;
Lawandy, SN ;
El-Wakeel, AA .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2000, 39 (01) :1-21
[9]  
Soliman A. A.-W., 1985, PROPELLANTS EXPLOS P, V10, P82
[10]   Evaluation of malonanilides as new stabilizers for double-base propellants. (I) [J].
Zayed, MA ;
Soliman, AAW ;
Hassan, MA .
JOURNAL OF HAZARDOUS MATERIALS, 2000, 73 (03) :237-244