Near-electrode and transient processes in liquid dielectrics

被引:48
作者
Zhakin, A. I. [1 ]
机构
[1] Kursk State Tech Univ, Kursk 305040, Russia
关键词
D O I
10.1070/PU2006v049n03ABEH002012
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Electron transfer kinetics between an electrode and an electron acceptor in electrolytes, liquid dielectrics, and dense gases is comparatively analyzed for the case of a weak electric field. Near-electrode charge distribution patterns in a liquid dielectric (or a dense weekly conducting gas) exposed to an external high-voltage field are examined. It is shown that the quadratic dependence of current-voltage characteristics of the system is determined by the character of electron transitions from surface states. The transient processes involved are discussed, and characteristic formation times for steady-state near-electrode patterns are calculated.
引用
收藏
页码:275 / 295
页数:21
相关论文
共 98 条
[21]  
BROUCHE M, 1996, P 1996 IEEE 12 INT C, P130
[22]  
Caldin E. F., 1964, FAST REACTIONS SOLUT
[23]  
CASTELLANOS F, 1998, CISM COURSES LECT, V380, P1
[24]  
DAMASKIN BB, 1983, VVEDENIE ELEKTROKHIM
[25]  
DAVYDOV AS, 1963, KVANTOVAYA MEKHANIKA
[26]  
Delahay P., 1954, NEW INSTRUMENTAL MET
[27]  
Dikarev B., 1999, Proceedings of 1999 IEEE 13th International Conference on Dielectric Liquids (ICDL'99) (Cat. No.99CH36213), P33, DOI 10.1109/ICDL.1999.798861
[28]  
Dogonadze R. R., 1975, RUSS CHEM REV, V44, P938
[29]  
DOGONADZE RR, 1969, PROGR SCI SER ELECTR, P5
[30]   ION INJECTION BY METALLIC ELECTRODES INTO LIQUID HYDROCARBONS OF HIGH-RESISTIVITY [J].
FELICI, N ;
GOSSE, JP .
REVUE DE PHYSIQUE APPLIQUEE, 1979, 14 (05) :629-633