Tungsten-based catalysts for the oxidation of cyclohexanol: The effect of phase transfer catalysts

被引：4

作者：

Bai, Guoyi ^{[1
]}

Jia, Chunwei ^{[1
]}

Xu, Kai ^{[1
]}

Fan, Xinxin ^{[1
]}

Ning, Huisen ^{[1
]}

Zhao, Kuixia ^{[2
]}

机构：

[1] Hebei Univ, Key Lab Chem Biol Hebei Province, Coll Chem & Environm Sci, Baoding 071002, Hebei, Peoples R China

[2] Guangdong Tech Coll Water Resources & Elect Engn, Guangzhou 510635, Guangdong, Peoples R China

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 2009年 / 96卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Tungsten-based catalysts; phase transfer catalysts; cyclohexanol; oxidation; AQUEOUS HYDROGEN-PEROXIDE; SELECTIVE OXIDATION; EFFICIENT CATALYSTS; ALCOHOLS; HETEROPOLYANIONS; DEHYDROGENATION; EPOXIDATION; KETONES; LIQUID; OXYGEN;

D O I：

10.1007/s11144-009-5391-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidation of cyclohexanol with hydrogen peroxide in the presence of tungsten-based catalysts was studied in this paper. The effect of phase transfer catalysts was discussed and clarified. [CTA](9)[SbW9O33] showed the best activity and good recyclability with a conversion over 95%.

引用

页码：109 / 116

页数：8

共 19 条

[1] Effect of carriers and additives on the activity and stability of copper-based catalysts for the dehydrogenation of cyclohexanol [J].

Bai, Guoyi ;

Wang, Hailong ;

Ning, Huisen ;

He, Fei ;

Chen, Guofeng .

REACTION KINETICS AND CATALYSIS LETTERS, 2008, 94 (02) :375-383

[2]

Bogdal D, 2000, SYNLETT, P143

[3] Highly efficient catalysts in directed oxygen-transfer processes:: Synthesis, structures of novel manganese-containing heteropolyanions, and applications in regioselective epoxidation of dienes with hydrogen peroxide [J].

Bösing, M ;

Nöh, A ;

Loose, I ;

Krebs, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (29) :7252-7259

[4] Oxidation of alcohols with hydrogen peroxide catalyzed by a new imidazolium ion based phosphotungstate complex in ionic liquid [J].

Chhikara, BS ;

Chandra, R ;

Tandon, V .

JOURNAL OF CATALYSIS, 2005, 230 (02) :436-439

[5] Oxidation of hydrophobic alcohols using aqueous hydrogen peroxide over amphiphilic silica particles loaded with titanium(IV) oxide as a liquid-liquid phase-boundary catalyst [J].

Choi, KM ;

Ikeda, S ;

Ishino, S ;

Ikeue, K ;

Matsumura, M ;

Ohtani, B .

APPLIED CATALYSIS A-GENERAL, 2005, 278 (02) :269-274

[6] Cobalt(II)-catalyzed oxidation of alcohols into carboxylic acids and ketones with hydrogen peroxide [J].

Das, S ;

Punniyamurthy, T .

TETRAHEDRON LETTERS, 2003, 44 (32) :6033-6035

[7] THE ACCURACY OF ESTIMATION OF HYDROGEN PEROXIDE BY POTASSIUM PERMANGANATE TITRATION [J].

HUCKABA, CE ;

KEYES, FG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1948, 70 (04) :1640-1644

[8] [SbW9O33]-based polyoxometalate combined with a phase transfer catalyst:: A highly effective catalyst system for selective oxidation of alcohols with H2O2, and spectroscopic investigation [J].

Ingle, Rohit H. ;

Raj, N. K. Kala ;

Manikandan, P. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 262 (1-2) :52-58

[9] HYDROGEN-PEROXIDE OXIDATION CATALYZED BY HETEROPOLY ACIDS COMBINED WITH CETYLPYRIDINIUM CHLORIDE - EPOXIDATION OF OLEFINS AND ALLYLIC ALCOHOLS, KETONIZATION OF ALCOHOLS AND DIOLS, AND OXIDATIVE CLEAVAGE OF 1,2-DIOLS AND OLEFINS [J].

ISHII, Y ;

YAMAWAKI, K ;

URA, T ;

YAMADA, H ;

YOSHIDA, T ;

OGAWA, M .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (15) :3587-3593

[10] A DIRECT CONVERSION OF VIC-DIOLS INTO 1,2-DIKETONES WITH AQUEOUS HYDROGEN-PEROXIDE CATALYZED BY PEROXOTUNGSTOPHOSPHATE (PCWP) [J].

IWAHAMA, T ;

SAKAGUCHI, S ;

NISHIYAMA, Y ;

ISHII, Y .

TETRAHEDRON LETTERS, 1995, 36 (09) :1523-1526

← 1 2 →