Palladium-catalyzed R2(O)P directed C(sp2)-H acetoxylation

被引：67
作者：
Zhang, Heng [1 ]
Hu, Rong-Bin [1 ]
Zhang, Xiao-Yu [1 ]
Li, Shi-Xia [1 ]
Yang, Shang-Dong [1 ,2 ]
机构：
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
[2] Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 36期
关键词：
PALLADIUM(II)-CATALYZED ORTHO-ARYLATION; ARYL HYDROGEN PHOSPHATES; C-H FUNCTIONALIZATION; ORTHO-ALKENYLATION; COUPLING REACTIONS; BOND FORMATION; O BOND; OXIDATION; DIBENZOFURANS; ACTIVATION;
D O I：
10.1039/c4cc01238k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel and efficient Pd-catalyzed C-H acetoxylation is described. The approach uses R-2(O)P as a directing group to synthesize various substituted 2'-phosphorylbiphenyl-2-OAc compounds. Notably, the reaction exhibits smooth operation under mild conditions and shows good functional group tolerance. Products are obtained with high selectivity and yields.
引用
收藏
页码：4686 / 4689
页数：4
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