Hybridized cobalt/manganese vanadates as high-performance anodes in lithium ion battery

被引:9
作者
Xia, Dawei [1 ,2 ]
Yang, Jian [2 ]
Li, Mingqian [1 ]
Gao, Hongpeng [1 ]
Gong, Feng [3 ]
机构
[1] Univ Calif San Diego, Dept NanoEngn, La Jolla, CA 92093 USA
[2] Univ Elect Sci & Technol China, Sch Mat & Energy, Chengdu 611731, Peoples R China
[3] Southeast Univ, Sch Energy & Environm, Nanjing 211189, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
STORAGE PROPERTIES; GRAPHENE OXIDE; HOLLOW; NANOSHEETS; COMPOSITE; CAPACITY; PENCILS; COBALT;
D O I
10.1016/j.matlet.2020.128782
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
"Less cobalt" is an unstoppable trend especially in lithium ion batteries (LIBs). In this study, by doping Mn for cobalt vanadate through facile hydrothermal reaction, the novel mixed Co/Mn vanadates are obtained balancing performance and cost. The 67%Mn-based vanadates, of optimized element ratio, achieve a high initial discharge capacity of 1193 mAhg(-1) and maintain 935 mAhg(-1) after 500 cycles at 0.5 A/g. (C) 2020 Elsevier B.V. All rights reserved.
引用
收藏
页数:4
相关论文
共 25 条
[1]   Novel spherical cobalt/nickel mixed-vanadates as high-capacity anodes in lithium ion batteries [J].
Gong, Feng ;
Xia, Dawei ;
Zhou, Qiang ;
Liao, Jiaxuan ;
Wu, Mengqiang .
JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 766 :442-449
[2]   Systematic comparison of hollow and solid Co3V2O8 micro-pencils as advanced anode materials for lithium ion batteries [J].
Gong, Feng ;
Xia, Dawei ;
Bi, Cheng ;
Yang, Jian ;
Zeng, Wei ;
Chen, Cheng ;
Ding, Yuanli ;
Xu, Ziqiang ;
Liao, Jiaxuan ;
Wu, Mengqiang .
ELECTROCHIMICA ACTA, 2018, 264 :358-366
[3]   Preparation of co-doped spherical spinel LiMn2O4 cathode materials for Li-ion batteries [J].
He, XM ;
Li, JJ ;
Cai, Y ;
Wang, YW ;
Ying, JR ;
Jiang, CY ;
Wan, CR .
JOURNAL OF POWER SOURCES, 2005, 150 :216-222
[4]   An All-Fluorinated Ester Electrolyte for Stable High-Voltage Li Metal Batteries Capable of Ultra-Low-Temperature Operation [J].
Holoubek, John ;
Yu, Mingyu ;
Yu, Sicen ;
Li, Minqian ;
Wu, Zhaohui ;
Xia, Dawei ;
Bhaladhare, Pranjal ;
Gonzalez, Matthew S. ;
Pascal, Tod A. ;
Liu, Ping ;
Chen, Zheng .
ACS ENERGY LETTERS, 2020, 5 (05) :1438-1447
[5]   Cation-exchange synthesis of manganese vanadate nanosheets and its application in lithium-ion battery [J].
Hua, Kang ;
Li, Xiujuan ;
Fu, Zewei ;
Fang, Dong ;
Bao, Rui ;
Yi, Jianhong ;
Luo, Zhiping .
JOURNAL OF SOLID STATE CHEMISTRY, 2019, 273 :287-294
[6]   A method of increasing the energy density of layered Ni-rich Li[Ni1-2xCoxMnx]O2 cathodes (x=0.05, 0.1, 0.2) [J].
Kim, Jae-Hyung ;
Park, Kang-Joon ;
Kim, Suk Jun ;
Yoon, Chong S. ;
Sun, Yang-Kook .
JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (06) :2694-2701
[7]  
Larcher D, 2015, NAT CHEM, V7, P19, DOI [10.1038/NCHEM.2085, 10.1038/nchem.2085]
[8]   Li3VO4: A Promising Insertion Anode Material for Lithium-Ion Batteries [J].
Li, Huiqiao ;
Liu, Xizheng ;
Zhai, Tianyou ;
Li, De ;
Zhou, Haoshen .
ADVANCED ENERGY MATERIALS, 2013, 3 (04) :428-432
[9]   Cobalt in lithium-ion batteries [J].
Li, Matthew ;
Lu, Jun .
SCIENCE, 2020, 367 (6481) :979-980
[10]   30 Years of Lithium-Ion Batteries [J].
Li, Matthew ;
Lu, Jun ;
Chen, Zhongwei ;
Amine, Khalil .
ADVANCED MATERIALS, 2018, 30 (33)