Elution of ion exchange resins by use of ultrasonication

被引：19
作者：
Feng, D [1 ]
Aldrich, C [1 ]
机构：
[1] Univ Stellenbosch, Dept Chem Engn, ZA-7602 Stellenbosch, South Africa
来源：
HYDROMETALLURGY | 2000年 / 55卷 / 02期
关键词：
ion exchange; elution; ultrasound;
D O I：
10.1016/S0304-386X(99)00087-0
中图分类号：
TF [冶金工业];
学科分类号：
0806 ;
摘要：
The feasibility of using ultrasound to enhance the elution of three ion exchange resins was investigated. A laboratory-scale elution column immersed in an ultrasonic bath was used to investigate three elution systems. XAD7-Au (eluted with NaOH, at a pH of 10), IR120H-Cd (eluted with HCl) and A375-SO42- (eluted with saturated lime solutions). The physico-chemical stability of the resins was not affected adversely by sonication, with the exception of the XAD7 resin, which showed very slight degradation after prolonged exposure. Ultrasonic radiation improved the elution recoveries and kinetics considerably. This could possibly be attributed to an increase in counter-ion diffusive transport caused by acoustic vortex microstreaming, as well as the prevention of precipitation that can lead to the blockage of ion exchange sites. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：201 / 212
页数：12
相关论文
共 18 条
  • [1] ARKHANGELSKII ME, 1973, PHYSICAL PRINCIPLES, V2, P294
  • [2] BOLTO BA, 1987, WASTEWATER TREATMENT, P262
  • [3] Clifford D. A., 1990, WATER QUALITY TREATM, P561
  • [4] DORFNER K, 1972, ION EXCHANGES PROPER
  • [5] HELFFERICH F, 1962, KINETICS ION EXCHANG
  • [6] Inczedy J., 1966, ANAL APPL ION EXCHAN
  • [7] Ley S. V., 1989, ULTRASOUND SYNTHESIS
  • [8] Liu D, 1996, ENVIRON TOXIC WATER, V11, P195, DOI 10.1002/(SICI)1098-2256(1996)11:3<195::AID-TOX4>3.3.CO
  • [9] 2-C
  • [10] MUKHERJEE S, 1997, GEOTECH SPEC PUBL, V65, P122
12