Nucleophilicity scale for n- and π-nucleophiles

被引：36

作者：

Jaramillo, Paula

Fuentealba, Patricio

Perez, Patricia

机构：

[1] Univ Andres Bello, Fac Ecol & Recursos Nat, Dept Ciencias Quim, Santiago, Chile

[2] Univ Chile, Fac Ciencias, Dept Fis, Santiago 653, Chile

[3] Univ Chile, Fac Ciencias, Dept Quim, Santiago 653, Chile

来源：

CHEMICAL PHYSICS LETTERS | 2006年 / 427卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2006.06.066

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A recently introduced empirical nucleophilicity index for a series of n- and pi-nucleophiles was evaluated. The index is based on the frontier molecular orbital information of the nucleophile and its electrophilic partner. The model is validated against kinetic data of alkenes, phosphanes, phosphites and amines interacting with the corresponding electrophilic partner. The predictive character of this index is tested for some nucleophiles. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：421 / 425

页数：5

共 50 条

[1] Nucleophiles, nucleophilicity and relationship between nucleophilicity and basicity
Tripathy, Tridib
De, B. R.
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2009, 86 (10) : 1087 - 1092
[2] REACTION OF N-(ALKOXYCARBONYL)SACCHARINS WITH NUCLEOPHILES
MATSUMURA, N
MATSUYAMA, Y
OTSUJI, Y
IMOTO, E
NIPPON KAGAKU KAISHI, 1978, (04) : 582 - 586
[3] BEHAVIORS OF N-(DIALKYLAMINOMETHYL)IMIDES AND N-(DIAKYLAMINOMETHYL)-AMIDES TOWARD NUCLEOPHILES
MATSUDA, O
ITO, K
SEKIYA, M
CHEMICAL & PHARMACEUTICAL BULLETIN, 1974, 22 (05) : 1119 - 1125
[4] METHYL BASICITY AND NUCLEOPHILICITY - N- AND O-ALKYLATION OF CARBAMATES
AHMED, MG
ALDER, RW
JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (23): : 1389 - &
[5] How constant are Ritchie's constant selectivity relationships A general reactivity scale for n-, π-, and σ-nucleophiles
Mayr, H. (Herbert.Mayr@cup.uni-muenchen.de), 1600, American Chemical Society (125):
[6] How constant are Ritchie's "constant selectivity relationships"?: A general reactivity scale for n-, π-, and σ-nucleophiles
Minegishi, S
Mayr, H
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (01) : 286 - 295
[7] A design to prevent floating within the N scale of nucleophilicity
Bentley, T. William
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 2010, 23 (09) : 836 - 844
[8] Hydrogen Bonding Lowers Intrinsic Nucleophilicity of Solvated Nucleophiles
Chen, Xin
Brauman, John I.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (45) : 15038 - 15046
[9] Hydrogen bonding lowers intrinsic nucleophilicity of solvated nucleophiles
Chen, Xin
Brauman, John I.
Journal of the American Chemical Society, 2008, 130 (45): : 15038 - 15046
[10] Interaction of α-bromoacetylphenylacetonitrile with some N- and S-nucleophiles
Kovtunenko, V.A.
Kupchevskaya, I.P.
Kisil, V.M.
Ukrainskij Khimicheskij Zhurnal, 2001, 67 (11-12): : 36 - 41

← 1 2 3 4 5 →