Single-phased white-light emitting CaAl2Si2O8: Eu2+, Mn2+ phosphors prepared by a sol-gel method

被引:21
|
作者
Wang, Baoling [1 ]
Sun, Liuzheng [1 ]
Ju, Haidong [1 ]
Zhao, Shilong [1 ]
Deng, Degang [1 ]
Wang, Huanping [1 ]
Xu, Shiqing [1 ]
机构
[1] China Jiliang Univ, Coll Mat Sci & Engn, Hangzhou 310018, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Sol-gel; Phosphor; White LED; DIODE; LUMINESCENCE;
D O I
10.1007/s10971-009-1909-2
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
CaAl2Si2O8: Eu2+, Mn2+ phosphors have been prepared by a sol-gel method. X-ray diffractometer, spectrofluorometer and UV-Vis spectrometer were used to characterize structural and optical properties of the samples. The results indicate that anorthite (CaAl2Si2O8) directly crystallizes at 1000 A degrees C in the sol-gel process. CaAl2Si2O8: Eu2+, Mn2+ phosphors show two emission bands excited by ultraviolet light. Blue (around 415 nm) and yellow (around 575 nm) emissions originate from Eu2+ and Mn2+, respectively. With appropriate tuning of Mn2+ content, CaAl2Si2O8: Eu2+, Mn2+ phosphors exhibit different hues and relative color temperatures.
引用
收藏
页码:368 / 371
页数:4
相关论文
共 50 条
  • [31] Ba2Ca(B3O6)2:Eu2+,Mn2+: A potential tunable blue-white-red phosphors for white light-emitting diodes
    Xiao, F.
    Xue, Y. N.
    Ma, Y. Y.
    Zhang, Q. Y.
    PHYSICA B-CONDENSED MATTER, 2010, 405 (03) : 891 - 895
  • [32] Preparation and Photoluminescence Properties of SrAl2Si2O8:Eu2+ Phosphors for White LED
    Chen Li-Song
    Bai Zhao-Hui
    Li Jin-Wei
    Wang Pei
    Wang Peng-Fei
    Zhong Ying
    Shan Dong-Dong
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2010, 26 (08) : 1409 - 1414
  • [33] Emission properties of EU2+, Mn2+ in MAl2Si2O8 (M = Sr, Ba)
    Ye, Shi
    Liu, Zhong-Shi
    Wang, Xiu-Teng
    Wang, Jia-Guo
    Wang, Ling-Xuan
    Jing, Xi-Ping
    JOURNAL OF LUMINESCENCE, 2009, 129 (01) : 50 - 54
  • [34] Photoluminescent properties of single-phase white-light Ca8ZnGd (PO4)7:Eu2+,Mn2+ phosphor
    Bu, Xiaoya
    Liu, Yan-gai
    Wang, Baochen
    Mi, Ruiyu
    Wang, Ziyao
    Huang, Zhaohui
    CHEMICAL PHYSICS LETTERS, 2020, 743
  • [35] Crystal structure tailoring and luminescence tuning of Sr1-xBaxAl2Si2O8:Eu2+ phosphors for white-light-emitting diodes
    Wang, Baochen
    Wang, Ziyao
    Liu, Yangai
    Yang, Tao
    Huang, Zhaohui
    Fang, Minghao
    JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 776 : 554 - 559
  • [36] Sr2+ substitution for Ca2+ and Eu2+,Dy3+ co-doping enhance mechanoluminescence of CaAl2Si2O8 phosphors
    Fang, Hua
    Qiu, Gaojian
    Li, Jun
    Wang, Xusheng
    JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 763 : 267 - 272
  • [37] Energy transfer between Eu2+ and Mn2+ in long-afterglow phosphor CaAl2O4:Eu2+, Nd3+, and Mn2+
    Xu, Xuhui
    Wang, Yuhua
    Li, Yanqin
    Gong, Yu
    JOURNAL OF APPLIED PHYSICS, 2009, 105 (08)
  • [38] Structural and photoluminescent properties of nanosized BaMgAl10O17: Eu2+ blue-emitting phosphors prepared by sol-gel method
    Hao Van Bui
    Tu Nguyen
    Manh Cuong Nguyen
    Trong An Tran
    Ha Le Tien
    Hao Tam Tong
    Thi Kim Lien Nguyen
    Thanh Huy Pham
    ADVANCES IN NATURAL SCIENCES-NANOSCIENCE AND NANOTECHNOLOGY, 2015, 6 (03)
  • [39] Morphology control and photoluminescence of BaMgAl10O17:Eu2+, Mn2+ phosphors prepared by flux method
    Wang, Wenjie
    Liu, Bitao
    Wang, Yuhua
    Zhang, Zhiya
    Chen, Yousan
    Wei, Lan
    MATERIALS LETTERS, 2011, 65 (23-24) : 3580 - 3582
  • [40] Sr7.3Ca2.7(PO4)6F2:Eu2+, Mn2+: a novel single-phased white light-emitting phosphor for NUV-LEDs
    Ding, Jianyan
    Wu, Quansheng
    Li, Yanyan
    Long, Qiang
    Wang, Chuang
    Wang, Yuhua
    DALTON TRANSACTIONS, 2015, 44 (20) : 9630 - 9636