Cobalt and iron supported on carbon nanofibers as catalysts for Fischer-Tropsch synthesis

被引：48

作者：

Antonio Diaz, Jose ^{[1
]}

Akhavan, Hasti ^{[2
,3
]}

Romero, Amaya ^{[4
]}

Maria Garcia-Minguillan, Alba ^{[1
]}

Romero, Rubi ^{[5
]}

Giroir-Fendler, A. ^{[2
,3
]}

Luis Valverde, Jose ^{[1
]}

机构：

[1] Univ Castilla La Mancha, Fac Ciencias & Tecnol Quim, Dept Ingn Quim, E-13071 Ciudad Real, Spain

[2] Univ Lyon 1, F-69622 Villeurbanne, France

[3] IRCELYON, CNRS, UMR 5256, F-69622 Villeurbanne, France

[4] Univ Castilla La Mancha, Escuela Ingenieros Agran, E-13071 Ciudad Real, Spain

[5] UAEMex UNAM, Ctr Conjunto Invest Quim Sustentable, Toluca 50200, Mexico

来源：

FUEL PROCESSING TECHNOLOGY | 2014年 / 128卷

关键词：

Fischer-Tropsch; Carbon nanofibers; Cobalt; Iron; Bimetallic catalysts; GAS-PHASE HYDROGENATION; BIMETALLIC CATALYSTS; PLATINUM CATALYSTS; CO; CINNAMALDEHYDE;

D O I：

10.1016/j.fuproc.2014.08.005

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Cobalt and/or iron supported on carbon nanofibers were prepared and used as monometallic or bimetallic catalysts for Fischer-Tropsch synthesis at 523 K and 20 bar. Catalysts were characterized by ICP, N-2 adsorption-desorption, TPR, XRD and XPS. Characterization results revealed that cobalt and iron had a synergetic effect: cobalt particles were better dispersed in presence of iron, and the latter was reduced to Fe in a higher extent due to the presence of the former. Catalytic results revealed that cobalt content played an important role in the catalytic conversion of CO. This way, the higher the content in cobalt, the higher the CO conversions were observed. Thus, sample 15Co/CNF presented the highest CO conversion. However, the presence of iron in bimetallic catalysts avoided an excessive production of CH4. The bimetallic sample with the highest Co loading (10Co5Fe/CNF) was the most active catalyst for the FTS reaction, because it led to the highest yield of longchained hydrocarbons. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：417 / 424

页数：8

共 34 条

[1] Correlation between Fischer-Tropsch catalytic activity and composition of catalysts [J].

Ali, Sardar ;

Zabidi, Noor Asmawati Mohd ;

Subbarao, Duvvuri .

CHEMISTRY CENTRAL JOURNAL, 2011, 5

[2] Aqueous phase hydrogenation of substituted phenyls over carbon nanofibre and activated carbon supported Pd [J].

Anderson, J. A. ;

Athawale, A. ;

Imrie, F. E. ;

McKenna, F. -M. ;

McCue, A. ;

Molyneux, D. ;

Power, K. ;

Shand, M. ;

Wells, R. P. K. .

JOURNAL OF CATALYSIS, 2010, 270 (01) :9-15

[3] Preparation of Fischer-Tropsch cobalt catalysts supported on carbon nanofibers and silica using homogeneous deposition-precipitation [J].

Bezemer, GL ;

Radstake, PB ;

Koot, V ;

van Dillen, AJ ;

Geus, JW ;

de Jong, KP .

JOURNAL OF CATALYSIS, 2006, 237 (02) :291-302

[4] Investigation of promoter effects of manganese oxide on carbon nanofiber-supported cobalt catalysts for Fischer-Tropsch synthesis [J].

Bezemer, GL ;

Radstake, PB ;

Falke, U ;

Oosterbeek, H ;

Kuipers, HPCE ;

van Dillen, A ;

de Jong, KP .

JOURNAL OF CATALYSIS, 2006, 237 (01) :152-161

[5] Studies with a precipitated iron Fischer-Tropsch catalyst reduced by H2 or CO [J].

Bian, GZ ;

Oonuki, A ;

Koizumi, N ;

Nomoto, H ;

Yamada, M .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 186 (1-2) :203-213

[6] Bimetallic catalysts for the Fischer-Tropsch reaction [J].

Calderone, V. Roberto ;

Shiju, N. Raveendran ;

Ferre, Daniel Curulla ;

Rothenberg, Gadi .

GREEN CHEMISTRY, 2011, 13 (08) :1950-1959

[7] Fischer-Tropsch synthesis: Comparison of performances of iron and cobalt catalysts [J].

Davis, Burtron H. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (26) :8938-8945

[8] Fischer-Tropsch synthesis on mono- and bimetallic Co and Fe catalysts in fixed-bed and slurry reactors [J].

de la Pena O'Shea, V. A. ;

Alvarez-Galvan, M. C. ;

Campos-Martin, J. M. ;

Fierro, J. L. G. .

APPLIED CATALYSIS A-GENERAL, 2007, 326 (01) :65-73

[9] Surface and structural features of Co-Fe oxide nanoparticles deposited on a silica substrate [J].

de la Pena O'Shea, Victor A. ;

Alvarez-Galvan, M. Consuelo ;

Campos-Martin, Jose M. ;

Menendez, Nieves N. ;

Tornero, Jesus D. ;

Fierro, Jose L. G. .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (24) :5057-5068

[10] Design of supported cobalt catalysts with maximum activity for the Fischer-Tropsch synthesis [J].

den Breejen, Johan P. ;

Sietsma, Jelle R. A. ;

Friedrich, Heiner ;

Bitter, Johannes H. ;

de Jong, Krijn P. .

JOURNAL OF CATALYSIS, 2010, 270 (01) :146-152

← 1 2 3 4 →