Accessing the inaccessible: discrete multinuclear coordination complexes and selective anion binding attainable only by tethering ligands together

被引：17

作者：

Ahmed, Basil M. ^{[1
]}

Mezei, Gellert ^{[1
]}

机构：

[1] Western Michigan Univ, Dept Chem, Kalamazoo, MI 49008 USA

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 06期

基金：

美国国家科学基金会;

关键词：

MAGNETIC-PROPERTIES; BISDIAZO-ALKANE; PYRAZOLATE; NANOJARS; COPPER(II); CLUSTER; MIXTURES; IONS;

D O I：

10.1039/c6cc09197k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel multimetallic copper pyrazolate complexes, inaccessible using simple pyrazole ligands due to competing, alternative structural motifs, can be obtained by locking pairs of pyrazole ligands together with ethylene tethers. Nanojars based on this tethered pyrazole ligand display unexpected total selectivity for the carbonate over the sulfate ion.

引用

页码：1029 / 1032

页数：4

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