An ammonia fuel cell using a mixed ionic and electronic conducting electrolyte

被引:48
作者
Maffei, N.
Pelletier, L.
Charland, J. P.
McFarlan, A.
机构
[1] Nat Resources Canada, CANMET, Mat Technol Lab, Ottawa, ON K1A 0E4, Canada
[2] Nat Resources Canada, CANMET Energy Technol Ctr, Ottawa, ON K1A 1M1, Canada
关键词
ammonia; europium doped barium cerate; fuel cells;
D O I
10.1016/j.jpowsour.2006.06.056
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The performance characteristics of fuel cells based on proton conducting BaCeO3 solid electrolyte doped with europium is reported. Fuel cells were operated for up to 200 h with both hydrogen and ammonia individually as fuel. Results show that the performance of the cell is the same irrespective of the fuel used. The open circuit voltage of the cells was lower than the theoretically expected value due to the presence of significant electronic conduction. Nevertheless, the data show that a fuel cell incorporating a europium doped barium cerate electrolyte operated on ammonia fuel is a viable alternative to fuel cells utilizing hydrocarbon fuels as sources of hydrogen. Crown Copyright (c) 2006 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:165 / 167
页数:3
相关论文
共 13 条
[1]  
GAY SE, 2003, FUEL CELLS TECHNOLOG
[2]   PROTON CONDUCTION IN SINTERED OXIDES AND ITS APPLICATION TO STEAM ELECTROLYSIS FOR HYDROGEN-PRODUCTION [J].
IWAHARA, H ;
ESAKA, T ;
UCHIDA, H ;
MAEDA, N .
SOLID STATE IONICS, 1981, 3-4 (AUG) :359-363
[3]   Protonic conduction in Zr-substituted BaCeO3 [J].
Katahira, K ;
Kohchi, Y ;
Shimura, T ;
Iwahara, H .
SOLID STATE IONICS, 2000, 138 (1-2) :91-98
[4]  
KINOSHITA K, 1994, ENCY CHEM TECHNOL, V11, P1098
[5]   An intermediate temperature direct ammonia fuel cell using a proton conducting electrolyte [J].
Maffei, N ;
Pelletier, L ;
Charland, JP ;
McFarlan, A .
JOURNAL OF POWER SOURCES, 2005, 140 (02) :264-267
[6]  
MARICLE DL, 1991, Patent No. 5001021
[7]   An intermediate-temperature ammonia fuel cell using Gd-doped barium cerate electrolyte [J].
McFarlan, A ;
Pelletier, L ;
Maffei, N .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (06) :A930-A932
[8]   CERAMIC FUEL-CELLS [J].
MINH, NQ .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1993, 76 (03) :563-588
[9]   HYDROGEN AND FOSSIL-FUELS [J].
ROTHSTEIN, J .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1995, 20 (04) :283-286
[10]  
SIMBECK DR, 2002, NRELSR54032525 US DO