Photo-cross-linked Poly(thioether-co-carbonate) Networks Derived from the Natural Product Quinic Acid

被引：21
|
作者：
Link, Lauren A. [1 ,2 ,3 ]
Lonnecker, Alexander T. [1 ,2 ,3 ]
Hearon, Keith [4 ]
Maher, Cameron A. [4 ]
Raymond, Jeffery E. [1 ,2 ,3 ]
Wooley, Karen L. [1 ,2 ,3 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
[2] Texas A&M Univ, Dept Chem Engn, College Stn, TX 77842 USA
[3] Texas A&M Univ, Dept Mat Sci & Engn, College Stn, TX 77842 USA
[4] Texas A&M Univ, Dept Biomed Engn, College Stn, TX 77842 USA
来源：
ACS APPLIED MATERIALS & INTERFACES | 2014年 / 6卷 / 20期
基金：
美国国家科学基金会;
关键词：
quinic acid; polycarbonates; renewable polymers; thiol-ene chemistry; photo-cross-linking; IN-VITRO DEGRADATION; BIODEGRADABLE POLYMERS; POLYCARBONATES; RESOURCES; CHEMISTRY;
D O I：
10.1021/am506087e
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Polycarbonate networks derived from the natural product quinic acid that can potentially return to their natural building blocks upon hydrolytic degradation are described herein. Solvent-free thiol-ene chemistry was utilized in the copolymerization of tris(alloc)quinic acid and a variety of multifunctional thiol monomers to obtain poly(thioether-co-carbonate) networks with a wide range of achievable thermomechanical properties including glass transition temperatures from -18 to +65 degrees C and rubbery moduli from 3.8 to 20 MPa. The network containing 1,2-ethanedithiol expressed an average toughness at 25 and 63 degrees C of 1.08 and 2.35 MJ/m(3), respectively, and an order-of-magnitude increase in the average toughness at 37 degrees C of 15.56 MJ/m(3).
引用
收藏
页码：17370 / 17375
页数：6
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