Oxidation of Benzyl Alcohol and Carbon Monoxide Using Gold Nanoparticles Supported on MnO2 Nanowire Microspheres

被引：46

作者：

Alhumaimess, Mosaed ^{[1
,2
]}

Lin, Zhongjie ^{[1
]}

He, Qian ^{[3
]}

Lu, Li ^{[3
]}

Dimitratos, Nickolaos ^{[1
]}

Dummer, Nicholas F. ^{[1
]}

Conte, Marco ^{[1
]}

Taylor, Stuart H. ^{[1
]}

Bartley, Jonathan K. ^{[1
]}

Kiely, Christopher J. ^{[2
]}

Hutchings, Graham J. ^{[1
]}

机构：

[1] Cardiff Univ, Sch Chem, Cardiff Catalysis Inst, Cardiff CF10 3AT, S Glam, Wales

[2] Aljouf Univ, Coll Sci, Dept Chem, Sakaka, Saudi Arabia

[3] Lehigh Univ, Dept Mat Sci & Engn, Bethlehem, PA 18015 USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 06期

基金：

英国工程与自然科学研究理事会;

关键词：

benzyl alcohol oxidation; CO oxidation; gold catalysis; heterogeneous catalysis; nanomaterials; LOW-TEMPERATURE OXIDATION; SOLVENT-FREE OXIDATION; HYDROGEN-PEROXIDE; CATALYTIC-OXIDATION; PALLADIUM CATALYSTS; CRYSTAL PHASE; CO OXIDATION; AU; WATER; CERIA;

D O I：

10.1002/chem.201303355

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

MnO2 was synthesised as a catalyst support material using a hydrothermal method. This involved reacting MnSO4 center dot H2O and (NH4)(2)S2O8 at 120 degrees C for a range of crystallisation times, which affords control over the morphology and phase composition of the MnO2 formed. Gold was deposited on these supports using sol-immobilisation, impregnation and deposition precipitation methods, and the resultant materials were used for the oxidation of benzyl alcohol and carbon monoxide. The effect of the support morphology on the dispersion of the gold nanoparticles and the consequent effect on the catalytic performance is described and discussed.

引用

页码：1701 / 1710

页数：10

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