Lignin-based multiwall carbon nanotubes

被引：34

作者：

Gindl-Altmutter, Wolfgang ^{[1
]}

Koehnke, Janea ^{[1
]}

Unterweger, Christoph ^{[2
]}

Gierlinger, Notburga ^{[3
]}

Keckes, Jozef ^{[4
]}

Zalesak, Jakub ^{[4
]}

Rojas, Orlando J. ^{[5
]}

机构：

[1] BOKU Univ Nat Resources & Life Sci, Dept Mat Sci & Proc Engn, A-3430 Vienna, Tulln, Austria

[2] Wood K Puls Kompetenzzentrum Holz GmbH, A-4040 Linz, Austria

[3] BOKU Univ Nat Resources & Life Sci, Dept Nanobiotechnol, A-1190 Vienna, Austria

[4] Univ Leoben, Dept Mat Phys, A-8700 Leoben, Austria

[5] Aalto Univ, Sch Chem Engn, Dept Bioprod & Biosyst, FI-00076 Aalto, Finland

来源：

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING | 2019年 / 121卷

基金：

欧洲研究理事会; 奥地利科学基金会;

关键词：

Carbon nanotubes and nanofibers; Lignin; RAMAN-SPECTROSCOPY; POROUS CARBON; KRAFT LIGNIN; GRAPHENE; NANOCELLULOSES; FRACTIONATION; MECHANISM; CELLULOSE;

D O I：

10.1016/j.compositesa.2019.03.026

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Carbon particles were produced by carbonization of perfectly spherical, sub-micron beads obtained from Kraft lignin. While the bulk of the particles consisted of carbon with only moderate structural order, high-resolution transmission electron microscopy revealed the presence of highly ordered multilayered carbon structures adhering to the surface of the carbon spheres. Besides irregularly shaped multiwall carbon, well-defined multiwall carbon nanotubes were identified. Energy dispersive x-ray analysis hints at a catalytic action of metallic impurities present in lignin in the synthesis of these lignin-based carbon nanostructures. Lignin-based multiwall carbon nanotubes are considered of high interest with regard to providing bio-based alternatives for fossil-based high-performance materials.

引用

页码：175 / 179

页数：5

共 39 条

[1] High-Throughput Synthesis of Lignin Particles (∼30 nm to ∼2μm) via Aerosol Flow Reactor: Size Fractionation and Utilization in Pickering Emulsions [J].

Ago, Mariko ;

Huan, Siqi ;

Borghei, Maryam ;

Raula, Janne ;

Kauppinen, Esko I. ;

Rojas, Orlando J. .

ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (35) :23302-23310

[2] Lignin-Based Electrospun Nanofibers Reinforced with Cellulose Nanocrystals [J].

Ago, Mariko ;

Okajima, Kunihiko ;

Jakes, Joseph E. ;

Park, Sunkyu ;

Rojas, Orlando J. .

BIOMACROMOLECULES, 2012, 13 (03) :918-926

[3] Multiwall carbon nanotubes: Synthesis and application [J].

Andrews, R ;

Jacques, D ;

Qian, DL ;

Rantell, T .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (12) :1008-1017

[4] Recent advances in low-cost carbon fiber manufacture from lignin [J].

Baker, Darren A. ;

Rials, Timothy G. .

JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 130 (02) :713-728

[5] Lignin from Micro- to Nanosize: Production Methods [J].

Beisl, Stefan ;

Miltner, Angela ;

Friedl, Anton .

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2017, 18 (06)

[6] Nanocellulose Patents Trends: A Comprehensive Review on Patents on Cellulose Nanocrystals, Microfibrillated and Bacterial Cellulose [J].

Charreau, Hernan ;

Foresti, Maria L. ;

Vazquez, Analia .

RECENT PATENTS ON NANOTECHNOLOGY, 2013, 7 (01) :56-80

[7] Skipping Oxidative Thermal Stabilization for Lignin-Based Carbon Nanofibers [J].

Cho, Mijung ;

Karaaslan, Muzaffer ;

Chowdhury, Sudip ;

Ko, Frank ;

Renneckar, Scott .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (05) :6434-6444

[8] New insights into the structure and composition of technical lignins: a comparative characterisation study [J].

Constant, Sandra ;

Wienk, Hans L. J. ;

Frissen, Augustinus E. ;

de Peinder, Peter ;

Boelens, Rolf ;

van Es, Daan S. ;

Grisel, Ruud J. H. ;

Weckhuysen, Bert M. ;

Huijgen, Wouter J. J. ;

Gosselink, Richard J. A. ;

Bruijnincx, Pieter C. A. .

GREEN CHEMISTRY, 2016, 18 (09) :2651-2665

[9] Influence of the Carbonization Process on Activated Carbon Properties from Lignin and Lignin-Rich Biomasses [J].

Correa, Catalina Rodriguez ;

Stollovsky, Moritz ;

Hehr, Tobias ;

Rauscher, Yannik ;

Rolli, Birgit ;

Kruse, Andrea .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2017, 5 (09) :8222-8233

[10] Carbon nanotubes: Synthesis, integration, and properties [J].

Dai, HJ .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (12) :1035-1044

← 1 2 3 4 →