A square-planar organoiron(III) compound with a spin-admixed state

被引：41
作者：
Alonso, Pablo J.
Arauzo, Ana B.
Fornies, Juan
Garcia-Monforte, M. Angeles
Martin, Antonio
Martinez, Jesus I.
Menjon, Babil
Rillo, Conrado
Saiz-Garitaonandia, Jose J.
机构：
[1] Univ Zaragoza, Inst Ciencia Mat Aragon, Zaragoza, Spain
[2] CSIC, Zaragoza, Spain
[3] Univ Basque Country, Fac Ciencias & Tecnol, Dept Fis Aplicada 2, E-48080 Bilbao, Spain
[4] Univ Zaragoza, Serv Instrumentac Cient, Zaragoza, Spain
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 40期
关键词：
EPR spectroscopy; homoleptic compounds; iron; magnetic properties; Moessbauer spectroscopy;
D O I：
10.1002/anie.200601774
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Square-planar iron(III) species bearing no axial ligands can still behave as spin-admixed systems (S=3/2,5/2). The highly unusual homoleptic σ-organoiron complex [Li(thf)4][Fe III(C6Cl5)4] (see anion in picture; green Cl, gray C) is an example of such a system. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码：6707 / 6711
页数：5
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