Aqua(2,2′-diamino-4,4′-bi-1,3-thiazole-κ2N,N)-(oxydiacetato-κ3O,O′,O")cobalt(II) dihydrate

被引：6
作者：
Shen, YH [1 ]
Liu, JG [1 ]
Xu, DJ [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷
关键词：
D O I：
10.1107/S1600536804011924
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Co(C4H4O5)(C6H6N4S2)(H2O)] . 2H(2)O, contains one Co-II complex and two water molecules in the asymmetric unit. The tridentate oxydiacetate dianion meridionally chelates a Co atom, and both five-membered chelate rings assume an envelope conformation. Diaminobithiazole chelates the Co atom, in a planar configuration. Parallel thiazole rings of neighboring complex molecules are separated by 3.504 (5) Angstrom, suggesting the existence of pi-pi stacking interactions.
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页码：M842 / M844
页数：3
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