A Facile Route to C2-Substituted Imidazolium Ionic Liquids

被引：22

作者：

Ennis, Elliot ^{[1
]}

Handy, Scott T. ^{[1
]}

机构：

[1] Middle Tennessee State Univ, Dept Chem, Murfreesboro, TN 37132 USA

来源：

MOLECULES | 2009年 / 14卷 / 06期

基金：

美国国家科学基金会;

关键词：

ionic liquids; N-heterocyclic carbenes; alkylation; imidazolium cation; substitution;

D O I：

10.3390/molecules14062235

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A convenient route for the preparation of C2-substituted imidazolium ionic liquids is reported. This method involves the alkylation of N-heterocyclic carbenes, which are readily generated from the C2-unsubstituted imidazolium ionic liquids. It works well for non-functionalized alkyl chlorides, and less well for alkyl bromides and iodides, likely due to competing elimination reactions. The resulting C2-substituted salts can be transformed into ionic liquids via standard anion metathesis reactions.

引用

页码：2235 / 2245

页数：11

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