Influence of grain size effect on electrical properties of Cu6PS5I superionic ceramics

被引：44
作者：
Salkus, T. [1 ]
Kazakevicius, E. [1 ]
Banys, J. [1 ]
Kranjcec, M. [2 ]
Chomolyak, A. A. [3 ]
Neimet, Yu. Yu. [3 ]
Studenyak, I. P. [3 ]
机构：
[1] Vilnius Univ, LT-10222 Vilnius, Lithuania
[2] Univ Zagreb, Fac Geotech, Varazhdin 42000, Croatia
[3] Uzhgorod Natl Univ, UA-88000 Uzhgorod, Ukraine
来源：
SOLID STATE IONICS | 2014年 / 262卷
关键词：
Superionic conductor; Ceramics; Impedance spectroscopy; Electrical conductivity; Size effect; Arrhenius law; Y THIN-FILMS; NANOCRYSTALLINE CERIA; ION CONDUCTORS; CONDUCTIVITY; TEMPERATURE; ARGYRODITES; TRANSPORT; CRYSTALS; BR; CL;
D O I：
10.1016/j.ssi.2013.10.040
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Cu6PS5I superionic ceramics were prepared from nanocrystalline powder, obtained by ball milling. From the structural investigations the average grain sizes of nanocrystalline powders were determined. Electrical conductivity measurements were carried out in the temperature interval 300-400 K and in the range of frequencies 10 Hz-3 GHz. The temperature and frequency dependences of electrical conductivity were analyzed. The influence of grain size effect on the electrical conductivity in Cu6PS5I superionic ceramics was studied. (C) 2013 Elsevier B.V. All rights reserved.
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收藏
页码：597 / 600
页数：4
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