Enhancement of the chromium removal behavior of Moringa oleifera activated carbon by chitosan and iron oxide nanoparticles from water

被引:100
作者
Bahador, Farahnaz [1 ]
Foroutan, Rauf [2 ]
Esmaeili, Hossein [3 ]
Ramavandi, Bahman [4 ,5 ]
机构
[1] Kherad Inst Higher Educ, Sch Chem Engn, Dept Chem Engn, Bushehr, Iran
[2] Univ Tabriz, Fac Chem & Petr Engn, Tabriz 5166616471, Iran
[3] Islamic Azad Univ, Dept Chem Engn, Bushehr Branch, Bushehr, Iran
[4] Bushehr Univ Med Sci, Syst Environm Hlth & Energy Res Ctr, Persian Gulf Biomed Sci Res Inst, Bushehr, Iran
[5] Bushehr Univ Med Sci, Fac Hlth & Nutr, Dept Environm Hlth Engn, Bushehr, Iran
关键词
Activated carbon; Chitosan; Magnetic nanoparticles; Moringa oleifera; Chromium ions; HEXAVALENT CHROMIUM; CR(VI) ADSORPTION; WASTE-WATER; PERFORMANCE; COMPOSITE;
D O I
10.1016/j.carbpol.2020.117085
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The effect of chitosan and Fe3O4 magnetic nanoparticles on the chromium adsorption property of Moringa oleifera activated carbon (AC) was explored. Various techniques were applied to reveal the properties of adsorbers to absorb chromium ions. A majority of the pollutant was removed at pH2 and 50 min. The kinetic behavior of the chromium uptake process was governed by the pseudo-second-order kinetic model (PSOKM). Based on the thermodynamic investigation, the chromium adsorption using all adsorbers was exothermic and spontaneous. The maximum single-layer adsorption capacity of AC, CS/AC, AC/Fe3O4, and CS/AC/Fe3O4 adsorbers was 56.78 mg/g, 114.80 mg/g, 121.70 mg/g, and 130.80 mg/g, respectively. The isotherm constants quantity highlighted that the Cr-adsorption process is optimal and physical. The acquired findings revealed that the modification of AC by chitosan and Fe(3)O(4 )nanoparticles increased the Cr adsorption. Adsorbers re-used up to 5 stages with a yield >90 %, which indicates that the composites are a promising option for Cr removal.
引用
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页数:9
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