Fabrication of cubic PtCu nanocages and their enhanced electrocatalytic activity towards hydrogen peroxide

被引：23

作者：

Tian, Liangliang ^{[1
]}

Zhong, Xiaohui ^{[1
]}

Hu, Wanping ^{[1
]}

Liu, Bitao ^{[1
]}

Li, Yunfeng ^{[2
]}

机构：

[1] Chongqing Univ Arts & Sci, Dept Res Ctr Mat Interdisciplinary Sci, Chongqing 402160, Peoples R China

[2] Univ Missouri, Dept Chem Engn, Columbia, MO 65211 USA

来源：

NANOSCALE RESEARCH LETTERS | 2014年 / 9卷

基金：

中国国家自然科学基金;

关键词：

Hydrogen peroxide; PtCu nanocage; Biosensor; HORSERADISH-PEROXIDASE; NANOPARTICLES; OXIDE;

D O I：

10.1186/1556-276X-9-68

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Cubic PtCu nanocages (NCs) were successfully synthesized through a redox reaction using cuprous oxide (Cu2O) as a sacrificial template and reducing agent. The porous PtCu NCs were composed of amounts of PtCu nanograins with an average particle size of 2.9 nm. The electrocatalytic performance of the PtCu NC electrode towards H2O2 was studied by cyclic voltammetry (CV) and chronoamperometry. The prepared PtCu NC electrode exhibited excellent electrocatalytic activity towards H2O2, with a wide liner range from 5 mu M to 22.25 mM, a relatively high sensitivity of 295.3 mu A mM(-1) cm(-2), and a low detection limit of 5 mu M (S/N =3). The hollow porous nanostructure has potential applications in biosensors.

引用

页码：1 / 5

页数：5

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