Recent Progress in Transition Metal-Catalyzed Coupling Reactions of Organotitanium Reagents

被引：1
作者：
Huang, Hui [1 ]
Li, Juanhua [1 ]
Liu, Kunming [1 ]
Liu, Jinbiao [1 ]
机构：
[1] Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 39卷 / 05期
基金：
中国国家自然科学基金;
关键词：
transition metal; catalysis; organotitanium reagent; coupling; HIGHLY DIASTEREOSELECTIVE ADDITION; LOW-VALENT TITANIUM; GRIGNARD-REAGENTS; ARYL HALIDES; ENANTIOSELECTIVE ADDITION; BIARYL COUPLINGS; ROOM-TEMPERATURE; BENZOIC-ACIDS; LK-ADDITION; COMPLEXES;
D O I：
10.6023/cjoc201810036
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Organotitanium proves to be one of ideal organometallic candidates because of its low price, non-toxicity, diversified types, excellent chemo-, regio- and stereo-selectivities. The reactivity of organotitanium reagent could be easily controlled by ligands of central titanium atom. Recently, the coupling reactions of organotitanium reagent have attracted extensive attention. This review summerized recent progress in transiton metal-catalyzed coupling reactons of organotitanium reagents concerning their types.
引用
收藏
页码：1293 / 1303
页数：11
相关论文
共 84 条
  • [1] COPPER-CATALYZED REACTIONS OF ORGANOTITANIUM REAGENTS - HIGHLY SN2' SELECTIVE AND ANTI-SELECTIVE AND DIASTEREOSELECTIVE AND CHEMOSELECTIVE ALKYLATION OF ALLYLIC CHLORIDES AND PHOSPHATES
    ARAI, M
    NAKAMURA, E
    LIPSHUTZ, BH
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (19) : 5489 - 5493
  • [2] Selective functionalization of arenes through the reaction of aryne-zirconocene complexes and enol ethers
    Barluenga, J
    Fernández, A
    Alvarez-Rodrigo, L
    Rodríguez, F
    Fañanás, FJ
    [J]. SYNLETT, 2005, (16) : 2513 - 2515
  • [3] Simple mixed Fe-Zn catalysts for the Suzuki couplings of tetraarylborates with benzyl halides and 2-halopyridines
    Bedford, Robin B.
    Hall, Mark A.
    Hodges, George R.
    Huwe, Michael
    Wilkinson, Mark C.
    [J]. CHEMICAL COMMUNICATIONS, 2009, (42) : 6430 - 6432
  • [4] Stepwise Modification of Titanium Alkoxy Chloride Compounds by Pyridine Carbinol
    Boyle, Timothy J.
    Ottley, Leigh Anna M.
    Rodriguez, Mark A.
    Sewell, Robin M.
    Alam, Todd M.
    McIntyre, Sarah K.
    [J]. INORGANIC CHEMISTRY, 2008, 47 (22) : 10708 - 10717
  • [5] Palladium-catalyzed coupling reactions of (ArCH2)Ti(O-i-Pr)3 with aromatic or heteroaromatic bromides
    Chang, Shu-Ting
    Li, Qinghan
    Chiang, Ruei-Tang
    Gau, Han-Mou
    [J]. TETRAHEDRON, 2012, 68 (21) : 3956 - 3962
  • [6] Extremely Efficient Cross-Coupling of Benzylic Halides with Aryltitanium Tris(isopropoxide) Catalyzed by Low Loadings of a Simple Palladium(II) Acetate/Tris(p-tolyl)phosphine System
    Chen, Chi-Ren
    Zhou, Shuangliu
    Biradar, Deepak Baburao
    Gau, Han-Mou
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2010, 352 (10) : 1718 - 1727
  • [7] Chen M. W., 1992, CHEM REAG, V14, P297
  • [8] Titanium complexes based on aminodiol ligands for the ring opening polymerization of L- and D,L-lactide
    Deivasagayam, Dakshinamoorthy
    Peruch, Frederic
    [J]. POLYMER, 2011, 52 (21) : 4686 - 4693
  • [9] The mechanisms of the Stille reaction
    Espinet, P
    Echavarren, AM
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (36) : 4704 - 4734
  • [10] Pd-catalyzed decarbonylative Heck olefination of aromatic carboxylic acids activated in situ with di-tert-butyl dicarbonate
    Goossen, LJ
    Paetzold, J
    Winkel, L
    [J]. SYNLETT, 2002, (10) : 1721 - 1723
123456789