Material characteristics and electrochemical performance of Sn-doped ZnO spherical-particle photoanode for dye-sensitized solar cells

被引:24
|
作者
Wang, Haohao [1 ]
Bhattacharjee, Ripon [2 ]
Hung, I-Ming [2 ]
Li, Langkai [1 ]
Zeng, Renjie [1 ]
机构
[1] Xiamen Univ, Dept Mat Sci & Engn, Xiamen 361005, Peoples R China
[2] Yuan Ze Univ, Dept Chem Engn & Mat Sci, Tao Yuan 320, Taiwan
关键词
Dye-sensitized solar cells; ZnO; Sn element; Spherical particle; THIN-FILMS; NANORODS; ARRAYS;
D O I
10.1016/j.electacta.2013.07.199
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The aim of this study was to examine the effects of Sn element on the characteristics and electrochemical properties of ZnO spherical-particle used as dye sensitized solar cells (DSSCs) photoanode. Spherical nanoparticles were synthesized via a polyol mediated precipitation method and four concentrations of Sn-Zn = 0, 3, 4, and 5 wt.% of photoelectrodes were prepared. Their structures, morphologies, photovoltaic performances and electrochemical properties were studied through XRD, SEM, TEM, J-V, IPCE and EIS. It was observed that the efficiency of dye-sensitized solar cells increased with the addition of Sn element and the SZO4 (Sn-Zn =4 wt.%) based DSSC had the highest power energy conversion efficiency of 0.80%, which is greatly increased compared to that of the DSSC based on ZnO (0.28%). (c) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:797 / 801
页数:5
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