Lattice parameter, density, and defect system of VOy

被引：6
|
作者：
Davydov, D. A. [1 ]
Rempel, A. A. [1 ]
机构：
[1] Russian Acad Sci, Inst Solid State Chem, Ural Div, Ekaterinburg 620219, Russia
来源：
INORGANIC MATERIALS | 2009年 / 45卷 / 06期
关键词：
VANADIUM-OXYGEN SYSTEM; DIFFRACTION; MONOXIDE;
D O I：
10.1134/S0020168509060156
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Vanadium monoxide, VO (y) has been studied within its homogeneity range using X-ray diffraction and pycnometric density measurements. The density and lattice parameter of VO (y) have been shown to vary in a complex manner with oxygen content near the stoichiometric composition VO1.0. The experimental data have been used to evaluate the vanadium and oxygen vacancy contents in VO (y) . We assume that two cubic phases close in lattice parameter coexist near the composition VO1.0 and form a solid solution.
引用
收藏
页码：666 / 670
页数：5
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