Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: synthesis of siloxanols

被引：56

作者：

Arzumanyan, Ashot V. ^{[1
]}

Goncharova, Irina K. ^{[1
]}

Novikov, Roman A. ^{[2
]}

Milenin, Sergey A. ^{[3
]}

Boldyrev, Konstantin L. ^{[3
]}

Solyev, Pavel N. ^{[2
]}

Tkachev, Yaroslav V. ^{[2
]}

Volodin, Alexander D. ^{[1
]}

Smol'yakov, Alexander F. ^{[1
,4
]}

Korlyukov, Alexander A. ^{[1
,5
]}

Muzafarov, Aziz M. ^{[1
,3
]}

机构：

[1] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, 28 Vavilova St, Moscow 119991, Russia

[2] Russian Acad Sci, Engelhardt Inst Mol Biol, 32 Vavilova St, Moscow 119991, Russia

[3] Russian Acad Sci, Enikolopov Inst Synthet Polymer Mat, 70 Profsoyuznaya St, Moscow 117393, Russia

[4] RUDN Univ, Fac Sci, 6 Miklukho Maklaya St, Moscow 117198, Russia

[5] NI Pirogov Russian Natl Res Med Univ, 1 Ostrovityanov St, Moscow 117997, Russia

来源：

GREEN CHEMISTRY | 2018年 / 20卷 / 07期

基金：

俄罗斯科学基金会;

关键词：

HYDROGEN; SILANOL; DENDRIMERS; ORGANOSILANES; ALKENYLATION; SILANEDIOLS; PRESSURE; SILICA; SITES; WATER;

D O I：

10.1039/c8gc00424b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly efficient preparative method for the synthesis of siloxanols based on aerobic Co(OAc)(2) or Cu(OAc)(2)/NHPI-catalyzed oxidation of hydride siloxanes using "green", commercially available, simple inexpensive reagents and mild reaction conditions has been proposed. This is a general reaction for the synthesis of mono-, oligo- and polymeric siloxanols with various structures (linear, branched and cyclic).

引用

页码：1467 / 1471

页数：5

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