Extending the series: Synthesis and characterization of a dicationic N-heterocyclic selenium carbene analogue

被引：43
|
作者：
Dutton, Jason L.
Tuononen, Heikki M.
Jennings, Michael C.
Ragogna, Paul J. [1 ]
机构：
[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
[2] Univ Jyvaskyla, Dept Chem, FI-40014 Jyvaskyla, Finland
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 39期
关键词：
D O I：
10.1021/ja064381d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The room-temperature reaction between the Dipp2DAB ligand, SnCl2, and SeCl4 results in the quantitative formation of a dicationic N-heterocyclic "carbenoid". This represents the first example of a chalcogenium dication that mimics the ubiquitous Arduengo-type carbenes; however, the electronic structure is significantly different. Copyright © 2006 American Chemical Society.
引用
收藏
页码：12624 / 12625
页数：2
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