Bismuth Based Hybrid Perovskites A3Bi2I9 (A: Methylammonium or Cesium) for Solar Cell Application

被引：1104
作者：
Park, Byung-Wook [1 ]
Philippe, Bertrand [2 ]
Zhang, Xiaoliang [1 ]
Rensmo, Hakan [2 ]
Boschloo, Gerrit [1 ]
Johansson, Erik M. J. [1 ]
机构：
[1] Uppsala Univ, Angstrom Lab, Dept Chem, SE-75120 Uppsala, Sweden
[2] Uppsala Univ, Dept Phys & Astron, Mol & Condensed Matter Phys, SE-75120 Uppsala, Sweden
来源：
ADVANCED MATERIALS | 2015年 / 27卷 / 43期
基金：
瑞典研究理事会;
关键词：
HIGH-PERFORMANCE; HALIDE PEROVSKITES; PHASE-TRANSITIONS; CS3BI2I9; HYSTERESIS; TRIHALIDE; CS3SB2I9; BAND;
D O I：
10.1002/adma.201501978
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Low-toxic bismuth-based perovskites are prepared for the possible replacement of lead perovskite in solar cells. The perovskites have a hexagonal crystalline phase and light absorption in the visible region. A power conversion efficiency of over 1% is obtained for a solar cell with Cs3Bi2I9 perovskite, and it is concluded that bismuth perovskites have very promising properties for further development in solar cells.
引用
收藏
页码：6806 / +
页数：9
相关论文
共 46 条
[1]   The phases of CS3Bi2I9 between RT and 190 K [J].
Arakcheeva, AV ;
Bonin, M ;
Chapuis, G ;
Zaitsev, AI .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1999, 214 (05) :279-283
[2]   The LT phase of Cs3Bi2I9 [J].
Arakcheeva, AV ;
Chapuis, G ;
Meyer, M .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2001, 216 (04) :199-205
[3]   Low-temperature processed meso-superstructured to thin-film perovskite solar cells [J].
Ball, James M. ;
Lee, Michael M. ;
Hey, Andrew ;
Snaith, Henry J. .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (06) :1739-1743
[4]   Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].
Burschka, Julian ;
Pellet, Norman ;
Moon, Soo-Jin ;
Humphry-Baker, Robin ;
Gao, Peng ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
NATURE, 2013, 499 (7458) :316-+
[5]   Oxygen-Induced Doping of Spiro-MeOTAD in Solid-State Dye-Sensitized Solar Cells and Its Impact on Device Performance [J].
Cappel, Ute B. ;
Daeneke, Torben ;
Bach, Udo .
NANO LETTERS, 2012, 12 (09) :4925-4931
[6]   CS3SB2I9 AND CS3BI2I9 WITH HEXAGONAL CS3CR2CL9 STRUCTURE TYPE [J].
CHABOT, B ;
PARTHE, E .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (FEB) :645-648
[7]   Photovoltaic effect in multiphase Bi-Mn-O thin films [J].
Chakrabartty, J. P. ;
Nechache, R. ;
Harnagea, C. ;
Rosei, F. .
OPTICS EXPRESS, 2014, 22 (01) :A80-A89
[8]   Switchable Ferroelectric Diode and Photovoltaic Effect in BiFeO3 [J].
Choi, T. ;
Lee, S. ;
Choi, Y. J. ;
Kiryukhin, V. ;
Cheong, S. -W. .
SCIENCE, 2009, 324 (5923) :63-66
[9]   Excitons versus free charges in organo-lead tri-halide perovskites [J].
D'Innocenzo, Valerio ;
Grancini, Giulia ;
Alcocer, Marcelo J. P. ;
Kandada, Ajay Ram Srimath ;
Stranks, Samuel D. ;
Lee, Michael M. ;
Lanzani, Guglielmo ;
Snaith, Henry J. ;
Petrozza, Annamaria .
NATURE COMMUNICATIONS, 2014, 5
[10]   Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells [J].
Eperon, Giles E. ;
Stranks, Samuel D. ;
Menelaou, Christopher ;
Johnston, Michael B. ;
Herz, Laura M. ;
Snaith, Henry J. .
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (03) :982-988
12345