Porous Hydrogen-Bonded Organic Frameworks

被引：108
作者：
Han, Yi-Fei [1 ,2 ,3 ]
Yuan, Ying-Xue [1 ,2 ,4 ]
Wang, Hong-Bo [1 ,2 ]
机构：
[1] Jianghan Univ, Sch Chem & Environm Engn, Minist Educ, Key Lab Optoelect Chem Mat & Devices, Wuhan 430056, Hubei, Peoples R China
[2] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China
[3] Univ Sci & Technol China, Dept Polymer Sci & Engn, Collaborat Innovat Ctr Chem Energy Mat iChEM, CAS Key Lab Soft Mat, Hefei 230026, Anhui, Peoples R China
[4] Huazhong Univ Sci & Technol, Dept Chem, Wuhan 430074, Hubei, Peoples R China
来源：
MOLECULES | 2017年 / 22卷 / 02期
基金：
中国国家自然科学基金;
关键词：
hydrogen bonds; organic porous frameworks; supramolecular self-assembly; MICROPOROUS MOLECULAR-CRYSTALS; CARBON-DIOXIDE; SUPRAMOLECULAR POLYMERS; SELECTIVE ADSORPTION; HEXAGONAL NETWORKS; FLUORESCENT-PROBE; SHAPE-MEMORY; TECTONICS; DERIVATIVES; ACID;
D O I：
10.3390/molecules22020266
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Ordered porous solid-state architectures constructed via non-covalent supramolecular self-assembly have attracted increasing interest due to their unique advantages and potential applications. Porous metal-coordination organic frameworks (MOFs) are generated by the assembly of metal coordination centers and organic linkers. Compared to MOFs, porous hydrogen-bonded organic frameworks (HOFs) are readily purified and recovered via simple recrystallization. However, due to lacking of sufficiently ability to orientate self-aggregation of building motifs in predictable manners, rational design and preparation of porous HOFs are still challenging. Herein, we summarize recent developments about porous HOFs and attempt to gain deeper insights into the design strategies of basic building motifs.
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页数：34
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