RETRACTED: Design and synthesis of magnetic Fe3O4@NFC-ImSalophCu nanocatalyst based on cellulose nanofibers as a new and highly efficient, reusable, stable and green catalyst for the synthesis of 1,2,3-triazoles (Retracted Article)

被引:50
作者
Kargar, Pouya Ghamari [1 ]
Bagherzade, Ghodsieh [1 ]
Eshghi, Hossein [2 ]
机构
[1] Univ Birjand, Dept Chem, Fac Sci, Birjand 97175615, Iran
[2] Ferdowsi Univ Mashhad, Fac Sci, Dept Chem, Mashhad, Razavi Khorasan, Iran
关键词
TEMPERATURE IONIC LIQUIDS; RECYCLABLE CATALYST; CLICK SYNTHESIS; 1,4-DISUBSTITUTED 1,2,3-TRIAZOLES; REGIOSELECTIVE SYNTHESIS; HETEROGENEOUS CATALYST; OXIDE NANOPARTICLES; COUPLING REACTIONS; PALLADIUM COMPLEX; COPPER;
D O I
10.1039/d0ra06251k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Fe3O4@NFC-ImSalophCu catalyst was used as a highly stable, reusable, active, green catalyst for the synthesis of 1,2,3-triazolesviaone-pot three-component reaction of phenacyl bromides, sodium azide and alkynes. A Cu(ii)-Schiff base complex containing an imidazolium ionic phase was prepared and decorated on core shell Fe3O4@NFC magnetic nanoparticles (Fe3O4@NFC-ImSalophCu) and was used as an efficient catalyst. The heterogeneous catalyst was characterized by FT-IR spectroscopy, FE-SEM, TEM, XRD spectroscopy, EDX spectroscopy, VSM, and ICP spectroscopy. This catalyst shows the dual function of the metal sites and imidazolium moieties. The catalytic system mentioned above also showed excellent activity in the synthesis of bis 1,4-disubstituted 1,2,3-triazoles. Moreover, the catalyst could be recycled and reused for four cycles without any decrease in its catalytic activity.
引用
收藏
页码:32927 / 32937
页数:11
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