Hybrid biocomposites based on calcium phosphate mineralization of self-assembled supramolecular hydrogels

被引:135
作者
Schnepp, Zoe A. C. [1 ]
Gonzalez-McQuire, Rosanna [1 ]
Mann, Stephen [1 ]
机构
[1] Univ Bristol, Sch Chem, Ctr Organized Matter Chem, Bristol BS8 1TS, Avon, England
关键词
D O I
10.1002/adma.200502545
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mineralization of small-molecule-based supramolecular hydrogels with calcium phosphate produces hybrid composites comprising interconnecting networks of calcified nanofilaments (see figure). Viscoelastic hybrid gels that exhibit enhanced thermal stability, stiffness, and critical strain are formed at low mineral contents, whereas extensive mineralization generates hard macroporous replicas of the supramolecular matrix.
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页码:1869 / +
页数:5
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