Effects of annealing on near-infrared shielding properties of Cs-doped tungsten oxide thin films deposited by electron beam evaporation

被引:23
作者
Long, Chak Seng [1 ]
Lu, Horng-Hwa [2 ]
Lii, Ding-Fwu [3 ]
Huang, Jow-Lay [1 ,4 ]
机构
[1] Natl Cheng Kung Univ, Dept Mat Sci & Engn, Tainan 701, Taiwan
[2] Natl Chin Yi Univ Technol, Dept Mech Engn, Taichung 41170, Taiwan
[3] Cheng Shiu Univ, Dept Elect Engn, Kaohsiung 833, Taiwan
[4] Natl Univ Kaohsiung, Dept Chem & Mat Engn, Kaohsiung 81148, Taiwan
关键词
Tungsten bronze; CsxWO3; Near-infrared shielding; Optical properties; OPTICAL PROPERTIES; BRONZE; ABSORPTION; CSXWO3; MICROSTRUCTURE; PARTICLES;
D O I
10.1016/j.surfcoat.2015.06.078
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Near-infrared (NIR) shielding properties are important for solar films. In this study, CsxWO3 films prepared using electron beam evaporation were characterized using X-ray diffraction, X-ray photoelectron spectroscopy, and spectrophotometry. The effects of annealing on NIR shielding properties and film microstructure were investigated. The results show that the NIR shielding properties of CsxWO3 films can be improved by annealing at 300-450 degrees C under pure H-2 atmosphere, the amorphous thin films being transformed to crystalline films. The CsxWO3 films annealed at 450 degrees C in pure H-2 atmosphere showed high transmittance of visible light (70%) and high NIR shielding ratio (99%). (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:75 / 79
页数:5
相关论文
共 27 条
[1]   Chromatic instabilities in cesium-doped tungsten bronze nanoparticles [J].
Adachi, Kenji ;
Ota, Yosuke ;
Tanaka, Hiroyuki ;
Okada, Mika ;
Oshimura, Nobumitsu ;
Tofuku, Atsushi .
JOURNAL OF APPLIED PHYSICS, 2013, 114 (19)
[2]  
Chen CJ, 2013, NANOSCALE RES LETT, V8, DOI [10.1186/1556-276X-8-57, 10.1186/1556-276X-8-453]
[3]   Studies on structural and electrical properties of sprayed SnO2:Sb films [J].
Elangovan, E ;
Shivashankar, SA ;
Ramamurthi, K .
JOURNAL OF CRYSTAL GROWTH, 2005, 276 (1-2) :215-221
[4]   Near-infrared absorption properties of RbxWO3 nanoparticles [J].
Guo, Chongshen ;
Yin, Shu ;
Dong, Qiang ;
Sato, Tsugio .
CRYSTENGCOMM, 2012, 14 (22) :7727-7732
[5]   Effects of Crystallization Atmospheres on the Near-Infrared Absorbtion and Electroconductive Properties of Tungsten Bronze Type MxWO3 (M = Na, K) [J].
Guo, Chongshen ;
Yin, Shu ;
Sato, Tsugio .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2012, 95 (05) :1634-1639
[6]   Discovery of an excellent IR absorbent with a broad working waveband: CsxWO3 nanorods [J].
Guo, Chongshen ;
Yin, Shu ;
Huang, Lijun ;
Yang, Lu ;
Sato, Tsugio .
CHEMICAL COMMUNICATIONS, 2011, 47 (31) :8853-8855
[7]   Synthesis of One-Dimensional Potassium Tungsten Bronze with Excellent near-Infrared Absorption Property [J].
Guo, Chongshen ;
Yin, Shu ;
Huang, Lijun ;
Satot, Tsugio .
ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (07) :2794-2799
[8]   Facile synthesis of homogeneous CsxWO3 nanorods with excellent low-emissivity and NIR shielding property by a water controlled-release process [J].
Guo, Chongshen ;
Yin, Shu ;
Yan, Mei ;
Sato, Tsugio .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (13) :5099-5105
[9]   Novel synthesis of homogenous CsxWO3 nanorods with excellent NIR shielding properties by a water controlled-release solvothermal process [J].
Guo, Chongshen ;
Yin, Shu ;
Zhang, Peilin ;
Yan, Mei ;
Adachi, Kenji ;
Chonan, Takeshi ;
Sato, Tsugio .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (38) :8227-8229
[10]   Crystal structure and electrical properties of new tungsten bronzes:: BxWO3 (0.01≤x≤0.08) [J].
Guo, Juan ;
Dong, Cheng ;
Yang, Lihong ;
Fu, Guangcai ;
Chen, Hong .
MATERIALS RESEARCH BULLETIN, 2007, 42 (07) :1384-1389