A Simple Theory of Mixtures for the Study of the Temperature Dependence of Thermo-structural Properties of Al-Ga Liquid Alloy

被引：0

作者：

Khanal, Kritika ^{[1
]}

Yadav, Shashit Kumart ^{[1
]}

Adhikari, Devendra ^{[1
]}

机构：

[1] Tribhuvan Univ, Dept Phys, Mahendra Morang Adarsh Multiple Campus, Biratnagar 56600, Nepal

来源：

JOURNAL OF PHYSICAL SCIENCE | 2020年 / 31卷 / 03期

关键词：

Simple theory of mixture; Al-Ga alloy; hetero-pairs; concentration fluctuation; diffusion coefficients; THERMODYNAMIC PROPERTIES; ORDER;

D O I：

10.21315/jps2020.31.3.7

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

A simple theory of mixtures for symmetric alloys was used to study the thermodynamic and structural properties of the Al-Ga alloy in the liquid state at 1023 K. The computed thermodynamic properties are in a very good agreement with the observed values and show that the alloy is weakly interacting. The computed structural properties show that the Al-Ga alloy is segregating in nature which is in agreement with the observed values. The excess free energy of mixing, activity of monomers and concentration fluctuation in the long wavelength limit was extrapolated to higher temperatures by optimising the temperature dependent parameters. As the temperature increases; the behaviour of the alloy shifts towards the ideality.

引用

页码：87 / 100

页数：14

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