Engineering of Mixed Host for High External Quantum Efficiency above 25% in Green Thermally Activated Delayed Fluorescence Device

被引:238
作者
Kim, Bo Seong [1 ]
Lee, Jun Yeob [1 ]
机构
[1] Dankook Univ, Dept Polymer Sci & Engn, Yongin 448701, Gyeonggi, South Korea
关键词
LIGHT-EMITTING-DIODES; BLUE; EMISSION;
D O I
10.1002/adfm.201303730
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Highly efficient thermally activated delayed fluorescence (TADF) devices are developed by engineering mixed host materials in the emitting layer. Mixed hosts with deep highest occupied molecular orbital and high singlet energy without any exciplex formation are ideal as the host material for the TADF organic light-emitting diodes. A high external quantum efficiency of 28.6% is achieved in the green TADF organic light-emitting diodes using a mixed host of 1,3-bis(N-carbazolyl) benzene: 1,3,5-tri[(3-pyridyl)-phen-3-yl] benzene and green emitting (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl) isophthalonitrile TADF emitter.
引用
收藏
页码:3970 / 3977
页数:8
相关论文
共 22 条
[1]   Highly efficient phosphorescent emission from organic electroluminescent devices [J].
Baldo, MA ;
O'Brien, DF ;
You, Y ;
Shoustikov, A ;
Sibley, S ;
Thompson, ME ;
Forrest, SR .
NATURE, 1998, 395 (6698) :151-154
[2]   Triplet Harvesting with 100% Efficiency by Way of Thermally Activated Delayed Fluorescence in Charge Transfer OLED Emitters [J].
Dias, Fernando B. ;
Bourdakos, Konstantinos N. ;
Jankus, Vygintas ;
Moss, Kathryn C. ;
Kamtekar, Kiran T. ;
Bhalla, Vandana ;
Santos, Jose ;
Bryce, Martin R. ;
Monkman, Andrew P. .
ADVANCED MATERIALS, 2013, 25 (27) :3707-3714
[3]   Organic light-emitting diodes employing efficient reverse intersystem crossing for triplet-to-singlet state conversion [J].
Goushi, Kenichi ;
Yoshida, Kou ;
Sato, Keigo ;
Adachi, Chihaya .
NATURE PHOTONICS, 2012, 6 (04) :253-258
[4]   Low roll-off of efficiency at high current density in phosphorescent organic light emitting diodes [J].
Kang, Jae-Wook ;
Lee, Se-Hyung ;
Park, Hyung-Dol ;
Jeong, Won-Ik ;
Yoo, Kyung-Mo ;
Park, Young-Seo ;
Kim, Jang-Joo .
APPLIED PHYSICS LETTERS, 2007, 90 (22)
[5]   Relationship between host energy levels and device performances of phosphorescent organic light-emitting diodes with triplet mixed host emitting structure [J].
Kim, Sung Hyun ;
Jang, Jyongsik ;
Lee, Jun Yeob .
APPLIED PHYSICS LETTERS, 2007, 91 (08)
[6]   High-efficiency organic light-emitting diodes utilizing thermally activated delayed fluorescence from triazine-based donor-acceptor hybrid molecules [J].
Lee, Sae Youn ;
Yasuda, Takuma ;
Nomura, Hiroko ;
Adachi, Chihaya .
APPLIED PHYSICS LETTERS, 2012, 101 (09)
[7]   Low Roll-Off and High Efficiency Orange Organic Light Emitting Diodes with Controlled Co-Doping of Green and Red Phosphorescent Dopants in an Exciplex Forming Co-Host [J].
Lee, Sunghun ;
Kim, Kwon-Hyeon ;
Limbach, Daniel ;
Park, Young-Seo ;
Kim, Jang-Joo .
ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (33) :4105-4110
[8]   Highly Efficient Organic Light-Emitting Diode Based on a Hidden Thermally Activated Delayed Fluorescence Channel in a Heptazine Derivative [J].
Li, Jie ;
Nakagawa, Tetsuya ;
MacDonald, James ;
Zhang, Qisheng ;
Nomura, Hiroko ;
Miyazaki, Hiroshi ;
Adachi, Chihaya .
ADVANCED MATERIALS, 2013, 25 (24) :3319-3323
[9]   Wide-Range Color Tuning of Iridium Biscarbene Complexes from Blue to Red by Different N∧N Ligands: an Alternative Route for Adjusting the Emission Colors [J].
Lu, Kun-Yi ;
Chou, Ho-Hsiu ;
Hsieh, Cheng-Han ;
Yang, Yu-Han Ou ;
Tsai, Huei-Ru ;
Tsai, Hsiu-Yun ;
Hsu, Lun-Chia ;
Chen, Chien-Yu ;
Chen, I-Chia ;
Cheng, Chien-Hong .
ADVANCED MATERIALS, 2011, 23 (42) :4933-4937
[10]   Enhanced Electroluminescence Efficiency in a Spiro-Acridine Derivative through Thermally Activated Delayed Fluorescence [J].
Mehes, Gabor ;
Nomura, Hiroko ;
Zhang, Qisheng ;
Nakagawa, Tetsuya ;
Adachi, Chihaya .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (45) :11311-11315