Synthesis of tetra- and triarylantimony fluorobenzoates

被引:4
作者
Sharutin, VV [1 ]
Sharutina, OK [1 ]
Bondar', EV [1 ]
Pakusina, AP [1 ]
Adonin, NY [1 ]
Starichenko, VF [1 ]
机构
[1] Blagoveshchensk State Pedag Univ, Blagoveshchensk, Russia
关键词
Hydrogen; Ether; Hydrogen Peroxide; Toluene; Elevated Temperature;
D O I
10.1023/A:1015439500222
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pentaarylantimonies Ar5Sb (Ar = Ph, p-Tol) was reacted with triarylantimony bis(perfluorobenzoate) and bis(3,4,5-trifluorobenzoate) in toluene at elevated temperature to obtain tetraarylantimony fluorobenzoates in 90% yield. Triarylantimony bis(fluorobenzoates) were prepared in an yield of up to 98% from triarylstibine and fluorobenzoic acid by oxidative addition in ether in the presence of hydrogen peroxide.
引用
收藏
页码:390 / 391
页数:2
相关论文
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[2]  
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[3]  
Sharutin VV, 1997, ZH OBSHCH KHIM+, V67, P1531
[4]  
Sharutina VV, 1997, ZH OBSHCH KHIM+, V67, P1536
[5]  
Thepe T.C., 1977, SCI WASHINGTON, V77, P134