Propeller-like multicomponent microstructures:: Self-assemblies of nanoparticles of poly(vinyl alcohol)-coated Ag and/or Cu2O

被引：37

作者：

Wu, Wei-Tai ^{[1
]}

Wang, Yusong ^{[1
]}

Shi, Lei ^{[1
]}

Pang, Wenmin ^{[1
]}

Zhu, Qingren ^{[1
]}

Xu, Guoyong ^{[1
]}

Lu, Fei ^{[1
]}

机构：

[1] Univ Sci & Technol China, Chinese Acad Sci, Hefei Natl Lab Phys Sci, Microscale Struct Res Lab, Anhua 230026, Peoples R China

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2006年 / 110卷 / 30期

关键词：

D O I：

10.1021/jp062121c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Novel propeller-like multicomponent microstructures, which are actually self-assemblies of nanoparticles of poly(vinyl alcohol) (PVA)-coated Ag and/or Cu2O, were synthesized in aqueous solution of amphiphilic polyvinylacetone (PVKA) (ketalization degree D-H = 0.549), via one-step in situ reduction of Ag+ and Cu2+ under gamma-ray irradiation, utilizing the low hydrolysis rate of PVKA in the dilute acidic solution. Herein, PVA chains are obtained from hydrolyzed PVKA. The reaction mechanism and the formation mechanism are proposed. The room temperature photoluminescence spectrum has also been applied to explore the optical property.

引用

页码：14702 / 14708

页数：7

共 40 条

[21] Self-assembly of mesoscopic metal-polymer amphiphiles [J].