[Cu2(HF2)(H2O)8][FeF6]•2H2O

被引：3

作者：

Le Bail, Armel ^{[1
]}

Mercier, Anne-Marie ^{[1
]}

机构：

[1] Univ Maine, CNRS, UMR 6010, Lab Oxydes & Fluorures, F-75085 Le Mans, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

BOND-VALENCE PARAMETERS; CRYSTAL-STRUCTURE;

D O I：

10.1107/S1600536809006874

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, octaaqua(hydrogenfluorido) dicopper(II) hexafluoridoferrate(III) dihydrate, was synthesized under hydrothermal conditions. The Cu atom is coordinated by one F and five O atoms within a highly distorted octahedron, forming dimeric [Cu-2(H2O)(8)HF2](3+) units by edge sharing. These units are hydrogen bonded to [FeF6](3-) anions and to an interstitial water molecule. The former feature Fe3+ on a special position ((1) over bar). The dimeric copper units are linked to adjacent dimers by F-H center dot center dot center dot F hydrogen bonds. Additional O-H center dot center dot center dot O and O-H center dot center dot center dot F hydrogen bonds help to consolidate the crystal packing.

引用

页码：I23 / U116

页数：12

共 15 条

[1] Brandenburg K., 1999, DIAMOND
[2] BOND-VALENCE PARAMETERS FOR SOLIDS
BRESE, NE
OKEEFFE, M
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 : 192 - 197
[3] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE
BROWN, ID
ALTERMATT, D
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG): : 244 - 247
[4] Farrugia L. J., 1997, J APPL CRYSTALLOGR, V30, P565, DOI [DOI 10.1107/S0021889897003117, 10.1107/S0021889897003117]
[5] CRYSTAL STRUCTURE OF LIHF2
FREVEL, LK
RINN, HW
[J]. ACTA CRYSTALLOGRAPHICA, 1962, 15 (03): : 286 - &
[6] Rubidium potassium hexafluorido-zirconate(IV) bis(hydrogen fluoride), Rb2-xKxZrF6•2HF (x=0.4171)
Gerasimenko, A. V.
Didenko, N. A.
Kavun, V. Ya.
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : i198
[7] The OsO3F+ and μ-F(OsO3F)2+ cations:: Their syntheses and study by Raman and 19F NMR spectroscopy and electron structure calculations and X-ray crystal structures of [OsO3F][PnF6] (Pn = As, Sb), [OsO3F][HF]2[AsF6], [OsO3F][HF][SbF6], and [OsO3F][Sb3F16]
Gerken, M
Dixon, DA
Schrobilgen, GJ
[J]. INORGANIC CHEMISTRY, 2002, 41 (02) : 259 - 277
[8] KUMMER S, 1987, Z NATURFORSCH B, V42, P1403
[9] LEBAIL A, 1992, EUR J SOL STATE INOR, V29, P183
[10] ROOM-TEMPERATURE STRUCTURE OF DIAQUAOCTAFLUOROCOPPER(II)DIIRON(III)
LEBLANC, M
FEREY, G
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 : 13 - 15

← 1 2 →