Adsorption of food dyes from aqueous solution by glutaraldehyde cross-linked magnetic chitosan nanoparticles

被引:144
作者
Zhou, Zhengkun [1 ,2 ]
Lin, Shiqi [2 ]
Yue, Tianli [1 ]
Lee, Tung-Ching [2 ]
机构
[1] Northwest A&F Univ, Coll Food Sci & Engn, Yangling 712100, Shaanxi, Peoples R China
[2] Rutgers State Univ, Dept Food Sci, New Brunswick, NJ 08901 USA
关键词
Food dye; Adsorption; Magnetic chitosan nanoparticles; Glutaraldehyde; Cytotoxicity; REACTIVE DYE; ACID DYE; REMOVAL; MECHANISM; CYTOTOXICITY; BIOSORPTION; ISOTHERMS; KINETICS; TARTRAZINE; TOXICITY;
D O I
10.1016/j.jfoodeng.2013.11.014
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Glutaraldehyde cross-linked magnetic chitosan nanoparticles (GMCNs) were prepared through crosslinking modification of magnetic chitosan nanoparticles (MCNs) using glutaraldehyde as crosslinker, that not only exhibited excellent food dyes adsorption performance, but also showed low cytotoxicity. Adsorption characteristics of GMCNs in FD&C Blue 1 and D&C Yellow 5 aqueous solutions have been studied and results indicated that the adsorption capacities were affected by initial pH values, initial dye concentrations and temperatures. Food dyes adsorption followed with the pseudo-second-order reaction, and equilibrium experiments were well fitted the Langmuir isotherm model. Maximum adsorption capacities of GMCNs displayed at pH 3.0 and at 25 degrees C, being up to 475.61 and 292.07 mg/g, for FD&C Blue 1 and D&C Yellow 5 respectively. Thermodynamic results demonstrated that the adsorption processes were spontaneous and exothermic. Furthermore, it was found that the GMCNs can be regenerated and reused through dye desorption in alkaline solution. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:133 / 141
页数:9
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