Hydroxylated Graphene-Sulfur Nanocomposites for High-Rate Lithium-Sulfur Batteries

被引：396
|
作者：
Zu, Chenxi [1 ]
Manthiram, Arumugam [1 ]
机构：
[1] Univ Texas Austin, Electrochem Energy Lab, Mat Sci & Engn Program, Austin, TX 78712 USA
来源：
ADVANCED ENERGY MATERIALS | 2013年 / 3卷 / 08期
关键词：
amorphous sulfur; electrochemical performance; hydroxylated graphene; lithium-sulfur batteries; CATHODE; OXIDE; CELL;
D O I：
10.1002/aenm.201201080
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A hydroxylated graphene-S nanocomposite exhibiting superior electrochemical performance at high rates is developed through a facile chemical deposition method at room temperature. The hydroxyl groups in graphene can interact with the sulfur-containing compounds, rendering sulfur in the amorphous state during the chemical deposition reaction and preventing polysulfide dissolution during cycling. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：1008 / 1012
页数：5
相关论文
共 50 条
  • [1] Facile Fabrication of Sulfur/Graphene Composite for High-Rate Lithium-Sulfur Batteries
    Chabu, Johnny Muya
    Zeng, Ke
    Walle, Maru Dessie
    You, Xiaolong
    Zhang, Mengyuan
    Li, Yajuan
    Liu, You-Nian
    CHEMISTRYSELECT, 2017, 2 (34): : 11035 - 11039
  • [2] High-rate lithium-sulfur batteries promoted by reduced graphene oxide coating
    Li, Nianwu
    Zheng, Mingbo
    Lu, Hongling
    Hu, Zibo
    Shen, Chenfei
    Chang, Xiaofeng
    Ji, Guangbin
    Cao, Jieming
    Shi, Yi
    CHEMICAL COMMUNICATIONS, 2012, 48 (34) : 4106 - 4108
  • [3] Facile fabrication of nanoporous graphene powder for high-rate lithium-sulfur batteries
    Zhuang, Huajie
    Deng, Wei
    Wang, Wei
    Liu, Zhaoping
    RSC ADVANCES, 2017, 7 (09): : 5177 - 5182
  • [4] A dual coaxial nanocable sulfur composite for high-rate lithium-sulfur batteries
    Li, Zhen
    Yuan, Lixia
    Yi, Ziqi
    Liu, Yang
    Xin, Ying
    Zhang, Zhaoliang
    Huang, Yunhui
    NANOSCALE, 2014, 6 (03) : 1653 - 1660
  • [5] Sulfur-Hydrothermal Carbon Composites for Cathode in High-Rate Lithium-Sulfur Batteries
    Li Yan-Bing
    Duan Xiao-Bo
    Han Ya-Miao
    Zhu Ding
    Huang Li-Wu
    Chen Yun-Gui
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2015, 31 (04) : 641 - 648
  • [6] Blocking Polysulfides in Graphene-Sulfur Cathodes of Lithium-Sulfur Batteries through Atomic Layer Deposition of Alumina
    Hong, Chulgi Nathan
    Kye, Daniel Kyungbin
    Mane, Anil U.
    Elam, Jeffrey W.
    Etacheri, Vinodkumar
    Pol, Vilas G.
    ENERGY TECHNOLOGY, 2019, 7 (12)
  • [7] Hierarchical carbon nanocages confining high-loading sulfur for high-rate lithium-sulfur batteries
    Lyu, Zhiyang
    Xu, Dan
    Yang, Lijun
    Che, Renchao
    Feng, Rui
    Zhao, Jin
    Li, Yi
    Wu, Qiang
    Wang, Xizhang
    Hu, Zheng
    NANO ENERGY, 2015, 12 : 657 - 665
  • [8] HIGH-RATE PRIMARY LITHIUM-SULFUR BATTERY
    ASKEW, BA
    HOLLAND, R
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1973, 120 (08) : C229 - C229
  • [9] Three-dimensional CNT/graphene-sulfur hybrid sponges with high sulfur loading as superior-capacity cathodes for lithium-sulfur batteries
    He, Jiarui
    Chen, Yuanfu
    Li, Pingjian
    Fu, Fei
    Wang, Zegao
    Zhang, Wanli
    JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (36) : 18605 - 18610
  • [10] Scotch-tape-like exfoliation of graphite assisted with elemental sulfur and graphene-sulfur composites for high-performance lithium-sulfur batteries
    Lin, Tianquan
    Tang, Yufeng
    Wang, Yaoming
    Bi, Hui
    Liu, Zhanqiang
    Huang, Fuqiang
    Xie, Xiaoming
    Jiang, Mianheng
    ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (04) : 1283 - 1290
12345